The electrons are still bound to the protons in the conducting material. They are in the conduction band, but they are still in a bound state. To move them to the other plate, you'd have to take them out of that bound state. Just because you have a conductor doesn't mean you have free electrons that are free to move as they wish.
Remember that electricity is moving electrons, but the electrons usually have to have a path to move through. In a conductor, they move along the conduction band (not out of it). In an insulator that has broken down, they move along the filaments of plasma. In a vacuum, you'd have to really just strip those electrons off the conductor and move them. With a strong enough electric field, I'm sure you can do that. But I don't know how strong of an electric field you would need. My intuition tells me the field must be very strong indeed.
The electric field, classically, of a proton at the typical separation distance of an electron (estimated 1 anstrom) is something like 10^11 N/C (N/C=V/m) so that should give you some indication of perhaps the numbers that are involved. Of course, quantum mechanics will obviously come into play here.
For comparison, the breakdown voltage of air is only 3,000,000 V/m.