Why Is Co2+ Pink?

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Discussion Overview

The discussion centers around the color of Co2+ ions, specifically addressing why they appear pink. Participants explore the nature of cobalt compounds and the factors influencing their color, including coordination chemistry and ligand effects.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant initially confuses Co2+ with CO2, leading to a clarification about the intended subject being cobalt ions.
  • Another participant suggests that the color of coordination compounds, such as Co2+, arises from the splitting of d-orbitals as explained by Crystal Field theory.
  • It is noted that the color of Co2+ can vary depending on the ligands surrounding the cobalt ion, with some ligands resulting in a pink or faintly red appearance.
  • One participant mentions that CoCl2 is blue, indicating that different compounds of cobalt can exhibit different colors.
  • There is a discussion about how the perceived color relates to the wavelengths of light absorbed and reflected by the ions.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the specifics of the color variations of Co2+ ions, as multiple factors such as ligands and coordination complexes are acknowledged as influencing the color. The discussion remains open with various viewpoints presented.

Contextual Notes

Some assumptions about the nature of cobalt compounds and the influence of ligands on color are present, but these are not fully explored or resolved within the discussion.

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why is Co2+ pink?
 
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sorry about that! you're right~
i mean cobalt ion...
thank you!
 
Adding to what HallsofIvy said, the colors of coordination compunds arises from the splitting of the d-orbitals as explained by the Crystal Field theory.
If you want more information, you can look up any good inorganic chemistry book like Concise Inorganic chemistry by J.D Lee. I found that coordination compounds are explained well in it.

EDIT: I assumed that you meant Cobalt 2+ complexes.
 
Last edited:
Oops, sorry about that - my fault. The 2+ should have caught my attention.

IIRC, in general the Co2+ is pink, or faintly red. On the other hand, chemweb has CoCl2 as being blue.

A lot may depend on the ligands surrounding Co, since it forms complex ions.

http://www.chemguide.co.uk/inorganic/transition/cobalt.html

http://www.chemguide.co.uk/inorganic/complexions/ligandexch.html

http://genchem.chem.wisc.edu/demonstrations/Gen_Chem_Pages/13equilpage/chloro_complexes_of_cobalt.htm

http://chemed.chem.purdue.edu/genchem/topicreview/bp/ch12/complex.html

The color depends on the lightwave wavelengths transmitted or reflected. Something red would generally absorb blue light (or light at the blue end of the visible spectrum) and reflect or transmit red light (or light at the red end).
 
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thank you very much! :)
 

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