Questions554
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I mean eV are something like 1.6x 10^-19 joules but somehow 7eV corresponds to 81121 K?? At that temperature you should have a lot more energy than 7eV! No?
Shyan said:Temperature is soemthing which can be defined for only many particle systems, you need to have at least a few hundread particles, if not more!
Then, the energy equivalent to a particular temperature is interpreted as the average energy of those particles. So when you say 7eV corresponds to 81121 K, it means that in a many particle system with such a temperature, the average energy of particles is 7eV. Some particles have much more energy and some much less.
Yeah, Boltzmann distribution tells you what fraction of the particles have a particular energy.Questions554 said:Ah cool, does this have to do with the mean of a Boltzmann distribution? This would mean 7eV being a vibrational energy?
Shyan said:Yeah, Boltzmann distribution tells you what fraction of the particles have a particular energy.
But all the energy doesn't have to be vibrational. It depends on the system. You may have a monatomic gas which can only have translational degrees of freedom. Or you may have something like a water molecule which can rotate around several axis and also has some vibrational degrees of freedom too. Of course the translational degrees of freedom are still present.