I haven't found a solution, but let me make clear that I have understood this correctly. You are defining a norm on ##\mathbb{R}[x]## by defining ##||P(x)|| = \sup_{t \in \mathbb{R}} e^{-|t|} |P(t)|##. This defines a metric on ##\mathbb{R}[x]##. Then you are defining multiplication maps ##\psi_{A(x)} : \mathbb{R}[x] \to \mathbb{R}[x]## for polynomials ##A(x) \in \mathbb{R}[x]## by putting ##\psi_{A(x)}(P(x)) = A(x)P(x)##. For constant polynomials ##A(x) = a_0##, these functions are clearly continuous. And the question is whether constant polynomials are the only polynomials ##A(x)## for which the corresponding multiplication map is continuous?
My attempt was trying to find a sequence of polynomials ##P_r(x)## of degree ##r## such that ##||P_r(x)|| \leq 1## for each ##r##, and then try to show that ##\psi_{A(x)}## is not continuous at ##0##. The idea is to find an appropriate sequence of such ##P_r(x)##'s such that ##||P_r(x)A(x)||## grows without bound as ##r## gets larger for any nonconstant polynomial ##A(x)##. In this case, choose ##\epsilon = 1##, and assume a ##\delta > 0## exists such that ##||P(x)|| < \delta \Rightarrow ||P(x)A(x)|| < 1##. Then ##||\frac{\delta}{2} P_r(x)|| \leq \frac{\delta}{2} < \delta##, but ##||\frac{\delta}{2} P_r(x)A(x)||## grows without bound, which shows that ##\psi_{A(x)}## is not continuous at ##0##.
For example, in the case of ##A(x) = x##, define ##P_r(x) = \frac{e^r}{r^r}x^r##. Then ##||P_r(x)|| = \frac{e^r}{r^r} \sup_{t \in \mathbb{R}} e^{-|t|} |t^r|##. To find this maximum value, we can clearly assume that ##t \geq 0## by symmetry. So to find the maximum value, we differentiate ##e^{-t}t^r## and get ##e^{-t}(rt^{r-1}-t^r)##. This expression is ##0## when ##t = r##, in which case the maximum value is ##\frac{e^r}{r^r} e^{-r}r^r = 1## (of course ##t = 0## is a minimum value). On the other hand, ##||P_r(x)A(x)|| = \frac{e^r}{r^r} \sup_{t \in \mathbb{R}} e^{-|t|} |t^{r+1}|##. Similarly, we differentiate and get the equation ##e^{-t}((r+1)t^{r}-t^{r+1}) = 0##. Here ##t = r+1##. But then the maximum value is ##\frac{e^r}{r^r} e^{-(r+1)} (r+1)^{r+1} = e^{-1}(1+ \frac{1}{r})^r (r+1) \geq e^{-1}(r+1)##. But ##\lim_{r \to \infty} e^{-1}(r+1) = \infty##. Thus the condition I described above is satisfied, and this proves that ##\phi_{x}## is not continuous at ##0##.
I do not know a proof for general nonconstant polynomials ##A(x)##, but the above example might be adapted.