Solve Thermodynamics Problem: Q12, W12, W21 & Entropy Change

In summary, the closed system starts at state 1 with 3 kg of R-134a at 10 °C and 90 kPa. It then undergoes an internally reversible, isothermal process until it reaches state 2 with a volume of 0.056 m3. The system then returns to state 1 by an irreversible process with a heat transfer of +3.2 kJ. The values needed to determine the Q12, W12, W21, and entropy change for each process can be found by analyzing the diagrams. It is recommended to seek further help or resources to solve this problem.
  • #1
ashkash
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Homework Statement



A closed system contains 3 kg of R-134a at 10 °C and 90 kPa (state 1), and undergoes an internally reversible, isothermal process until the volume of the R-134a reaches 0.056 m3 (state 2). The system returns to state 1 by an irreversible process and the heat transfer for the return process is +3.2 kJ. Determine Q12, W12, W21 and the entropy change for each process.


Homework Equations





The Attempt at a Solution



I do not know how to go about doing this. Any help will be appreciated. thanks.
 
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  • #2
Start out by drawing an T-s, P-V, and T-V diagram, to better see the cycle
 
  • #3


I would begin by first understanding the given information and identifying any relevant equations or concepts from thermodynamics. From the problem statement, we are given the initial state (state 1) of the closed system, which contains 3 kg of R-134a at 10 °C and 90 kPa. We are also told that the system undergoes an internally reversible, isothermal process until it reaches state 2, with a volume of 0.056 m3. This process is followed by an irreversible process that returns the system to state 1, with a heat transfer of +3.2 kJ.

To solve this problem, we can use the first law of thermodynamics, which states that the change in internal energy of a closed system is equal to the heat transfer into the system minus the work done by the system. Mathematically, this can be represented as ΔU = Q - W.

For the first process, we know that it is isothermal (meaning the temperature remains constant) and internally reversible. Therefore, we can use the equation for isothermal processes, which is Q = W. This means that the heat transfer (Q12) and the work done (W12) are equal in magnitude but opposite in sign. We can also use the ideal gas law to calculate the final pressure of the system at state 2, since the temperature and volume are given. Once we have the final pressure, we can calculate the work done by the system using the equation W = -∫PdV, where the negative sign indicates work done by the system. This will give us the value for W12.

For the second process, we are told that it is irreversible and that the heat transfer is +3.2 kJ. Therefore, we know that Q21 = +3.2 kJ. To calculate the work done (W21), we can use the same equation as before, but this time we need to know the final pressure at state 1. This can be found using the ideal gas law again, but with the initial temperature and volume given.

To calculate the entropy change for each process, we can use the equation ΔS = Q/T, where Q is the heat transfer and T is the temperature of the process. For the first process, since it is isothermal, the temperature remains constant and we can use the value given in the problem statement. For the second process, we need to calculate
 

1. How do I calculate Q12, W12, W21, and entropy change in a thermodynamics problem?

Q12, W12, W21, and entropy change are all values that can be calculated using the First Law of Thermodynamics and the Second Law of Thermodynamics. Q12 represents the heat transfer between two systems, W12 represents the work done by the first system, W21 represents the work done by the second system, and entropy change represents the change in entropy of the system. To calculate these values, you will need to know the initial and final states of the system, the amount of heat transferred, and the work done by each system.

2. What is the First Law of Thermodynamics?

The First Law of Thermodynamics is a fundamental principle in thermodynamics that states that energy cannot be created or destroyed, only transferred or converted from one form to another. It is often expressed as "energy in equals energy out" and is the basis for the conservation of energy principle.

3. What is the Second Law of Thermodynamics?

The Second Law of Thermodynamics is another fundamental principle in thermodynamics that states that the total entropy of a closed system will always increase over time, or remain constant in ideal cases where the system is in equilibrium. This law explains why certain processes, such as heat transfer, are irreversible and why systems tend to move towards a state of disorder.

4. How do I use the First and Second Laws of Thermodynamics to solve a problem?

To solve a thermodynamics problem using the First and Second Laws, you will need to identify the initial and final states of the system, determine the energy and work transfers, and apply the appropriate equations. The First Law can be used to calculate the change in internal energy of the system, while the Second Law can be used to calculate the change in entropy. It is important to carefully consider all sources and sinks of energy in the system and to use the correct signs for energy and work transfers.

5. What are some common mistakes to avoid when solving thermodynamics problems?

Some common mistakes to avoid when solving thermodynamics problems include not carefully considering all sources and sinks of energy in the system, not using the correct signs for energy and work transfers, and not converting units correctly. It is also important to check the final answer to ensure it makes physical sense and is in the correct units. It is recommended to carefully plan out the solution and double-check all calculations to avoid errors.

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