What is Spectroscopy: Definition and 332 Discussions
Spectroscopy is the study of the interaction between matter and electromagnetic radiation as a function of the wavelength or frequency of the radiation. In simpler terms, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum; indeed, historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO).
Spectroscopy, primarily in the electromagnetic spectrum, is a fundamental exploratory tool in the fields of physics, chemistry, and astronomy, allowing the composition, physical structure and electronic structure of matter to be investigated at the atomic, molecular and macro scale, and over astronomical distances. Important applications arise from biomedical spectroscopy in the areas of tissue analysis and medical imaging.
Am currently doing an undergraduate project work on 'estimation of radiological risk pose by U-238, th-232 and K-40 in rock samples' . The instrument I'll use are NaI(TI) crystal for scintilation were the gamma rays from the source(my rock samples) interact with the crystal through photoelectric...
Dear all,
I learn that photoelectron spectroscopy can measure the work function of solid semiconductors.
However, some research papers reported it measured the ionization potential of solid semiconductor nanoparticle films.
As we know there's obvious difference between the work function and...
Has anyone read or seen any articles that might highlight the techniques of Stimulated Raman Scattering Spectroscopy? Or just any knowledge on the process they would be able to share? I am having a tough time getting a hold on the process and if anyone has any useful information or articles that...
Hi!
In my lab class, we are using a photomultiplier to examine gamma ray emission lines and determine absorption coefficients of different radioactive materials.
Homework Statement
As we test for absorption (by layering on metals, incrementally increasing the thickness), we consider spectral...
Homework Statement
For our lab, we looked through the spectrometer to find the spectral values for Helium, which after being plugged into an excel spreadsheet, yielded an equation which I could use to find the wavelengths for Hydrogen. We were told to solve for R, which I did. However, at the...
When we want to view the spectrum of light emitted by a certain gas (via spectroscopy) how much voltage do those gas discharge tubes end up having? I know they are very high voltage, but how high exactly?
Now if I were to look at an incandescent light bulb through a spectroscope, I would see...
Hi
I'm a first year undergrad student studying Electronics. I am really interested in creating a working Laser Induced Breakdown Spectroscopy(LIBS) setup in my summer break which is June and July. I'm reading about it these days, although still scratching the surface. I'm confused whether I'll...
Homework Statement
The bond length of CO is 1.128 Å. At what wavenumbers do the first three rotational transitions appear
Homework Equations
μ= (m1m2/m1+m2)
I = μr0^2
B= h/(8∏^2)IbC
ΔE = 2B (J+1)
The Attempt at a Solution
For the first equation I got
(12 x 16) / 28 =...
I have read from time to time (e.g. Lakowicz) that the fluorescence spectrum of a substance is not generally influenced by the wavelength excitation source. On the other had there is a correlation as exemplified in excitation-emission matrix spectra for example.
The obvious case is for...
I have a question about energy reconstruction. I'm writing up a paper, and I'm trying to understand why this is the reason, before putting it in my paper. I know from experimental evidence that it is the case, though I would like to know if there is a reason.
Let's say you have a sufficiently...
Homework Statement The question states to identify which graph is associated with which molecule, which are CF4 and CF2Cl2. The graphs are measurements of infrared spectra, one has one peak while the other has two. It then asks to determine which symmetry labels are associated with each peak...
Hi guys,
So my project partner and I are struggling to solve a problem with our laser spectroscopy data for rubidium isotopes and I thought it may be a good idea to see if you could help us.
If you take a look at the attached image you will see that the blue line shows our doppler free...
Dear friends
I have a question regarding to polarized Raman spectroscopy. When we are talking about parallel and perpendicular electric field of the laser, is the magic angle 90° or 54.7°?
I'd be grateful if you could answer me as soon as possible.
Best wishes
Kasra
I am looking for an alpha detector to do an alpha spectroscopy (and maybe beta as well).
The rough setup is a vacuum tube with a detector in one end and a source in the other, possibly with a magnet in the middle.
I have googled around, but my problem is that I don't really know what is...
Hi all,
I'm relatively new to the forum, but excited to be a part of a community discussing physics, as I lack company to really discuss my research at my place of work (university), as I am a physicist working solely amongst chemical engineers.
I am using a UV-Vis spectrometer, with the...
Homework Statement
Hi. I'm starting to read about IR spectroscopy and I have a question. I know that there are 2 kinds of vibrational modes in molecules: bending and stretching, so in a molecule like water for example, how can I tell which one of the vibrational does it have?
What I mean...
Hello,
I'm currently a sophomore in high school and am interested in working on something to find methods of completely non-invasive toxin detection which I don't see out right now. I've noted that this is done by interpreting the spectra of different materials which could contain the...
Hi there. First time PF poster. I have a question about interpreting IR spectro graphs. I get the general idea of interpreting the sharpness and strength of the line but when I need to ID the pulse down I have to choose between \delta and \upsilon (or mabe its just v) version of the...
Homework Statement
The question relates to carbonic anhydrase with Zinc at the biosite. (1ca2 on protein data bank).
Q: Why can you not study the water bound to the zinc when the molecule is in an aqueous solution?
Homework Equations
n/a
The Attempt at a Solution
I've had a...
1. In a photoelectron spectroscopy experiment Ar is ionised, i.e. an electron
is removed from one of the single electron orbitals into the vacuum. An
Ar+ ion remains behind. Write down all possible electron configurations
and corresponding terms of the resulting Ar+ ion (assuming that the...
Hello,
My problem is as follows:
The lab I am working on requires the construction of a calibration curve from the measured absorbance of samples of known phenol concentration to intrapolate the phenol concentration of two unknown samples. I have constructed the calibration curve and...
Can something read, the amount of energy, reflected by the light to determine its properties?
Is there a scanner that also reads, the wavelength of the light reflected from an object?
Also is there a way to fix a particle so we could determine the angle of incoming radiation that has been...
Hi! I'm a little confused about simple spectroscopy. In typical absorption experiments, we scan the laser frequency w and get a anti-peak/dip in the transmitted intensity I(w) around a resonance frequency. The size of the dip, i.e. the population of the excited level, usually depends linearly on...
I made some frequency calculations in Gaussian (using various method/basis set combos) and I have to find which method/basis set combo is the most accurate by comparing the results to literature values. I got the calculated wavenumbers along with their intensities but my professor tells me I...
I was thinking of preparing applesauce for some type of spectroscopy( ex: Raman). I was thinking of testing it for arsenic. Does anyone have any idea what applesauce would dissolve in ( I realize this is more of a biology question).
thanks
I have asked a question about this before but this is a different question.
The experiment that my lab partner and I performed used a 360 degree rotating assembly which had the light source (Hydrogen and Sodium) and the telescope at opposite ends while the diffraction grating sat in the...
Homework Statement
a) Calculate the Doppler shift due to a relative velocity of 3cm/sec.
b) Fine \Delta E/E, where E = 14.4keV and \Delta E is the Doppler shift obtained in (a).
Homework Equations
\frac{f_{0}}{f_{s}}=\frac{c}{c+v_{s}}
The Attempt at a Solution
So I'm working on...
Hi,
I have finished an experiment about vibronic transitions for the N_2 molecule and I'd like to compare my results ( vibrational frequencies and dissociation energies of the electronic states interested in the N_2 second positive and N+_2 first negative band systems ) with the accepted...
I have been conducting liquid phase adsorption experiments of xylene and toluene using activated carbon. I made solutions at 2 concentrations (200ppm and 400ppm) of individual components of toluene and xylene in methanol, as a solvent.
Initially, the plan was to use Gas Chromatography to...
Hi all!
I'm doing undergrad research work using fluorescence spectroscopy on crystals. My adviser believes that we should be able to find new transitions via this method, but I'm rather unsure about how steady mental ground my adviser is sitting on, as he is very old.
Right now I am...
Indicate those of the following statements that are correct for the compound 13CH3OH
(The 13 in front of C is supposed to indicate carbon-13)
a. The carbon-13 spectrum will be a 1:2:1 triplet.
b. The proton NMR spectrum will be a 1:1 doublet and a broad singlet.
c. The broad singlet in the...
Hello there!
Im studying microwave spectroscopy, and I'm stuck because I don't see why the spacing between rotational energy levels increases as J does. Can anyone explain please?
Also, about IR, I see everywhere that the selction rule is Δv=±1. Correct me if I'm wrong but I'm guessing...
Ultrafast laser spectroscopy, as I know, is used for the determination of femtosecond events in condensed phases.
My question is, what applications do these discoveries have, or are they just for "research"?
Hi,
I'm a computer scientist w/ very little hardware experience. I've been playing with the idea of using NIRS for a brain computer interface.
The basic principle is pretty simple: You have a laser diode and a detector that is 2-3 cm away from the diode. Unfortunately I have almost no...
Okay, I'm havin trouble understanding the difference between NMR and spectrums.
As far as I know: in NMR you excite a nuclei from one state to another. The frequency of the energy absorbed is what we measure.
How is that related to normal spectrums and colour? For example, absorption of...
function: e^-(x^2/2)
operator: d^2/dx^2 -x^2
The answer key says the function is an eigenfunction of the operator with an eigenvalue of -6.
I can't figure out how to reach this conclusion. Also, Wolfram Alpha says d/dx(d/(dx)e^(-x^2/2)) = e^(-x^2/2) (x^2-1). Isn't this inconsistent with...
I've been looking at spectra from diatomic molecules. If I know the temperature of the material I'm looking at and I know which transition I want to look at how can I calculate what the observed flux (in Jansky) should be?
Also, what can I calculate from observed FWHM?
Thanks.
Dear PF,
I'm a graduate student working in an ultracold atomic phys lab. We're trying to build a new machine with Li6 as one of the components, but in order to cool it we need to do saturation absorption spectroscopy on a separate stand-alone cell in order to tell our lasers what frequencies...
Homework Statement
The Raman spectrum of ethene, obtained using 488.0nm radiation from a laser, shows an intense line at 540.0nm. Calculate the wavenumber for this vibration
I know that you get stokes, anti-stokes and rayleigh scattering. Not sure how to calculate the wavenumber though ...
Hi!
I have two (stupid) questions:
1) We can determine what elements are present in distant stars by studying their spectrum, right? But if the spectrum of some star is redshifted, wouldn't we be fooled into believing some elements to be present there that might not really be there, due to...
Homework Statement
Give two reasons why as molecular size increases does it become increasingly difficult to experimentally obtain well-resolved rotational spectra?
The Attempt at a Solution
Basically I know one reason. The energy levels become more tightly packed.
I have another...
For my advanced physics lab course this semester, I recently conducted an experiment using a hyper-pure germanium detector to measure the energy of gamma rays released upon the formation of deuterium (DF).
Essentially, I used a neutron source to bombard a hydrogen rich target (used both...
Hello, I am currently in an analytical chemistry course where I am required to write a report on Raman Spectroscopy. The typical description of Raman Spectroscopy is the excitation of an electron to a "virtual" state, whereupon it can relax to a non zero vibrational level in its ground...
In class we learned about the fundamentals behind RBS using a linear accelerator that accelerates He+ ions to 2MeV. We were then provided an example where those ions collided with a sample with layers of Silicon-Bismuth-Silicon, each of known thickness; and, we were then shown the corresponding...
Hi, I am new to this forum but I am an applied physics student and I'm working on a seminar on deep space spectroscopy. My question is actually on the equipment being used for my research.
I am using an SBIG ST-7 camera with a DSS-7 spectrograph and I've been running calibration studies with...
Hi,
I am currently in the process of writing up my lab reports and wanted to know how to report mass spectroscopy and elemental analysis in the RSC style.
In my report guidelines it suggests elemental analysis should be reported as follows:
"Shown in the form: Found: C, 63.1; H, 5.4...