What is Spectroscopy: Definition and 332 Discussions

Spectroscopy is the study of the interaction between matter and electromagnetic radiation as a function of the wavelength or frequency of the radiation. In simpler terms, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum; indeed, historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO).
Spectroscopy, primarily in the electromagnetic spectrum, is a fundamental exploratory tool in the fields of physics, chemistry, and astronomy, allowing the composition, physical structure and electronic structure of matter to be investigated at the atomic, molecular and macro scale, and over astronomical distances. Important applications arise from biomedical spectroscopy in the areas of tissue analysis and medical imaging.

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  1. M

    Gamma Spectroscopy for Estimating Radiological Risk in Rocks

    Am currently doing an undergraduate project work on 'estimation of radiological risk pose by U-238, th-232 and K-40 in rock samples' . The instrument I'll use are NaI(TI) crystal for scintilation were the gamma rays from the source(my rock samples) interact with the crystal through photoelectric...
  2. H

    The axes in Raman spectroscopy

    What are the axes(horizontal & vertical axes) in a Raman spectrum?
  3. L

    About photoelectron spectroscopy, work function, ionization potential

    Dear all, I learn that photoelectron spectroscopy can measure the work function of solid semiconductors. However, some research papers reported it measured the ionization potential of solid semiconductor nanoparticle films. As we know there's obvious difference between the work function and...
  4. O

    Stimulated Raman Scattering Spectroscopy

    Has anyone read or seen any articles that might highlight the techniques of Stimulated Raman Scattering Spectroscopy? Or just any knowledge on the process they would be able to share? I am having a tough time getting a hold on the process and if anyone has any useful information or articles that...
  5. L

    Absorption and Spectroscopy: Why increased counts at lower energies?

    Hi! In my lab class, we are using a photomultiplier to examine gamma ray emission lines and determine absorption coefficients of different radioactive materials. Homework Statement As we test for absorption (by layering on metals, incrementally increasing the thickness), we consider spectral...
  6. M

    Solving for R in Atomic Spectroscopy | Get Homework Help and Tips

    Homework Statement For our lab, we looked through the spectrometer to find the spectral values for Helium, which after being plugged into an excel spreadsheet, yielded an equation which I could use to find the wavelengths for Hydrogen. We were told to solve for R, which I did. However, at the...
  7. stripes

    Some questions about spectroscopy

    When we want to view the spectrum of light emitted by a certain gas (via spectroscopy) how much voltage do those gas discharge tubes end up having? I know they are very high voltage, but how high exactly? Now if I were to look at an incandescent light bulb through a spectroscope, I would see...
  8. A

    Laser Induced Breakdown Spectroscopy

    Hi I'm a first year undergrad student studying Electronics. I am really interested in creating a working Laser Induced Breakdown Spectroscopy(LIBS) setup in my summer break which is June and July. I'm reading about it these days, although still scratching the surface. I'm confused whether I'll...
  9. K

    Chemistry Spectroscopy (Molecular,Microwave)

    Homework Statement The bond length of CO is 1.128 Å. At what wavenumbers do the first three rotational transitions appear Homework Equations μ= (m1m2/m1+m2) I = μr0^2 B= h/(8∏^2)IbC ΔE = 2B (J+1) The Attempt at a Solution For the first equation I got (12 x 16) / 28 =...
  10. fsonnichsen

    Excitation Effects for Fluorescence Spectroscopy

    I have read from time to time (e.g. Lakowicz) that the fluorescence spectrum of a substance is not generally influenced by the wavelength excitation source. On the other had there is a correlation as exemplified in excitation-emission matrix spectra for example. The obvious case is for...
  11. C

    Energy Reconstruction in Gamma Spectroscopy

    I have a question about energy reconstruction. I'm writing up a paper, and I'm trying to understand why this is the reason, before putting it in my paper. I know from experimental evidence that it is the case, though I would like to know if there is a reason. Let's say you have a sufficiently...
  12. Q

    IR and Raman Spectroscopy With Vibrational Modes

    Homework Statement The question states to identify which graph is associated with which molecule, which are CF4 and CF2Cl2. The graphs are measurements of infrared spectra, one has one peak while the other has two. It then asks to determine which symmetry labels are associated with each peak...
  13. C

    Need help manipulating absorption spectroscopy data please

    Hi guys, So my project partner and I are struggling to solve a problem with our laser spectroscopy data for rubidium isotopes and I thought it may be a good idea to see if you could help us. If you take a look at the attached image you will see that the blue line shows our doppler free...
  14. S

    Polarized Raman Spectroscopy: Understanding the Magic Angle

    Dear friends I have a question regarding to polarized Raman spectroscopy. When we are talking about parallel and perpendicular electric field of the laser, is the magic angle 90° or 54.7°? I'd be grateful if you could answer me as soon as possible. Best wishes Kasra
  15. D

    Where to find an alpha radiation silicon detector? (alpha spectroscopy)

    I am looking for an alpha detector to do an alpha spectroscopy (and maybe beta as well). The rough setup is a vacuum tube with a detector in one end and a source in the other, possibly with a magnet in the middle. I have googled around, but my problem is that I don't really know what is...
  16. J

    Understanding molecular absorption of light (UV-Vis spectroscopy)

    Hi all, I'm relatively new to the forum, but excited to be a part of a community discussing physics, as I lack company to really discuss my research at my place of work (university), as I am a physicist working solely amongst chemical engineers. I am using a UV-Vis spectrometer, with the...
  17. R

    Question about organic spectroscopy (IR)

    Homework Statement Hi. I'm starting to read about IR spectroscopy and I have a question. I know that there are 2 kinds of vibrational modes in molecules: bending and stretching, so in a molecule like water for example, how can I tell which one of the vibrational does it have? What I mean...
  18. S

    Radiation Detection / Spectroscopy Project

    Hello, I'm currently a sophomore in high school and am interested in working on something to find methods of completely non-invasive toxin detection which I don't see out right now. I've noted that this is done by interpreting the spectra of different materials which could contain the...
  19. B

    What do the symbols \delta and \upsilon represent in IR spectroscopy?

    Hi there. First time PF poster. I have a question about interpreting IR spectro graphs. I get the general idea of interpreting the sharpness and strength of the line but when I need to ID the pulse down I have to choose between \delta and \upsilon (or mabe its just v) version of the...
  20. W

    Resonance raman spectroscopy for analysing metallobiosite

    Homework Statement The question relates to carbonic anhydrase with Zinc at the biosite. (1ca2 on protein data bank). Q: Why can you not study the water bound to the zinc when the molecule is in an aqueous solution? Homework Equations n/a The Attempt at a Solution I've had a...
  21. D

    Photoelectron spectroscopy experiment

    1. In a photoelectron spectroscopy experiment Ar is ionised, i.e. an electron is removed from one of the single electron orbitals into the vacuum. An Ar+ ion remains behind. Write down all possible electron configurations and corresponding terms of the resulting Ar+ ion (assuming that the...
  22. C

    Spectroscopy: Determining Phenol Concentration using Calibration curve

    Hello, My problem is as follows: The lab I am working on requires the construction of a calibration curve from the measured absorbance of samples of known phenol concentration to intrapolate the phenol concentration of two unknown samples. I have constructed the calibration curve and...
  23. T

    Difference between raman-spectroscopy and usual spectroscopy?

    What is the difference between raman-spectroscopy and usual spectroscopy?
  24. M

    Unlocking the Properties of Light: Geiger Spectroscopy and Wavelength Scanning

    Can something read, the amount of energy, reflected by the light to determine its properties? Is there a scanner that also reads, the wavelength of the light reflected from an object? Also is there a way to fix a particle so we could determine the angle of incoming radiation that has been...
  25. P

    Explaining linear spectroscopy from first principles

    Hi! I'm a little confused about simple spectroscopy. In typical absorption experiments, we scan the laser frequency w and get a anti-peak/dip in the transmitted intensity I(w) around a resonance frequency. The size of the dip, i.e. the population of the excited level, usually depends linearly on...
  26. M

    Zero point energy and IR spectroscopy

    I made some frequency calculations in Gaussian (using various method/basis set combos) and I have to find which method/basis set combo is the most accurate by comparing the results to literature values. I got the calculated wavenumbers along with their intensities but my professor tells me I...
  27. C

    Can Spectroscopy Be Used to Test Arsenic in Applesauce?

    I was thinking of preparing applesauce for some type of spectroscopy( ex: Raman). I was thinking of testing it for arsenic. Does anyone have any idea what applesauce would dissolve in ( I realize this is more of a biology question). thanks
  28. C

    Infrared spectroscopy and symmetry

    is it true to say that any molecule having a centre of symmetry will have the symmetric stretching IR inactive? thanks!
  29. GreenAce92

    Hydrogen Spectroscopy: Can You View 1st & 2nd Order on One Side Only?

    I have asked a question about this before but this is a different question. The experiment that my lab partner and I performed used a 360 degree rotating assembly which had the light source (Hydrogen and Sodium) and the telescope at opposite ends while the diffraction grating sat in the...
  30. A

    Doppler Shift as Applied to Nuclear Structure and Spectroscopy

    Homework Statement a) Calculate the Doppler shift due to a relative velocity of 3cm/sec. b) Fine \Delta E/E, where E = 14.4keV and \Delta E is the Doppler shift obtained in (a). Homework Equations \frac{f_{0}}{f_{s}}=\frac{c}{c+v_{s}} The Attempt at a Solution So I'm working on...
  31. R

    Electron Paramagnetic Resonance Spectroscopy

    I am a chemistry student and would like to know how to identify the g(parallell) and g(perpendicular peaks in the ESR spectra of copper(II) complexes.
  32. D

    Molecular spectroscopy and accepted literature values

    Hi, I have finished an experiment about vibronic transitions for the N_2 molecule and I'd like to compare my results ( vibrational frequencies and dissociation energies of the electronic states interested in the N_2 second positive and N+_2 first negative band systems ) with the accepted...
  33. F

    Using UV-Vis Spectroscopy to determine concentration

    I have been conducting liquid phase adsorption experiments of xylene and toluene using activated carbon. I made solutions at 2 concentrations (200ppm and 400ppm) of individual components of toluene and xylene in methanol, as a solvent. Initially, the plan was to use Gas Chromatography to...
  34. P

    Transitions using Fluorescence Spectroscopy

    Hi all! I'm doing undergrad research work using fluorescence spectroscopy on crystals. My adviser believes that we should be able to find new transitions via this method, but I'm rather unsure about how steady mental ground my adviser is sitting on, as he is very old. Right now I am...
  35. S

    Master Spectroscopy with 13CH3OH: Correct Statements Explained

    Indicate those of the following statements that are correct for the compound 13CH3OH (The 13 in front of C is supposed to indicate carbon-13) a. The carbon-13 spectrum will be a 1:2:1 triplet. b. The proton NMR spectrum will be a 1:1 doublet and a broad singlet. c. The broad singlet in the...
  36. C

    Rotational and vibrational spectroscopy

    Hello there! Im studying microwave spectroscopy, and I'm stuck because I don't see why the spacing between rotational energy levels increases as J does. Can anyone explain please? Also, about IR, I see everywhere that the selction rule is Δv=±1. Correct me if I'm wrong but I'm guessing...
  37. C

    What is the point of ultrafast laser spectroscopy?

    Ultrafast laser spectroscopy, as I know, is used for the determination of femtosecond events in condensed phases. My question is, what applications do these discoveries have, or are they just for "research"?
  38. S

    Need help building a Near Infrared Spectroscopy Device

    Hi, I'm a computer scientist w/ very little hardware experience. I've been playing with the idea of using NIRS for a brain computer interface. The basic principle is pretty simple: You have a laser diode and a detector that is 2-3 cm away from the diode. Unfortunately I have almost no...
  39. C

    Spectroscopy how does it work?

    Okay, I'm havin trouble understanding the difference between NMR and spectrums. As far as I know: in NMR you excite a nuclei from one state to another. The frequency of the energy absorbed is what we measure. How is that related to normal spectrums and colour? For example, absorption of...
  40. A

    Eigenvalue Question (p2.14 in Quantum Chemistry and Spectroscopy)

    function: e^-(x^2/2) operator: d^2/dx^2 -x^2 The answer key says the function is an eigenfunction of the operator with an eigenvalue of -6. I can't figure out how to reach this conclusion. Also, Wolfram Alpha says d/dx(d/(dx)e^(-x^2/2)) = e^(-x^2/2) (x^2-1). Isn't this inconsistent with...
  41. O

    Questions on diatomic spectroscopy

    I've been looking at spectra from diatomic molecules. If I know the temperature of the material I'm looking at and I know which transition I want to look at how can I calculate what the observed flux (in Jansky) should be? Also, what can I calculate from observed FWHM? Thanks.
  42. G

    Help please -- Li saturation absorption spectroscopy

    Dear PF, I'm a graduate student working in an ultracold atomic phys lab. We're trying to build a new machine with Li6 as one of the components, but in order to cool it we need to do saturation absorption spectroscopy on a separate stand-alone cell in order to tell our lasers what frequencies...
  43. B

    Raman spectroscopy help (simple)

    Homework Statement The Raman spectrum of ethene, obtained using 488.0nm radiation from a laser, shows an intense line at 540.0nm. Calculate the wavenumber for this vibration I know that you get stokes, anti-stokes and rayleigh scattering. Not sure how to calculate the wavenumber though ...
  44. V

    Astronomical spectroscopy and doppler shift.

    Hi! I have two (stupid) questions: 1) We can determine what elements are present in distant stars by studying their spectrum, right? But if the spectrum of some star is redshifted, wouldn't we be fooled into believing some elements to be present there that might not really be there, due to...
  45. B

    Quick rotational spectroscopy question(only need ideas/suggestions)

    Homework Statement Give two reasons why as molecular size increases does it become increasingly difficult to experimentally obtain well-resolved rotational spectra? The Attempt at a Solution Basically I know one reason. The energy levels become more tightly packed. I have another...
  46. N

    Gamma ray spectroscopy of deuteron formation

    For my advanced physics lab course this semester, I recently conducted an experiment using a hyper-pure germanium detector to measure the energy of gamma rays released upon the formation of deuterium (DF). Essentially, I used a neutron source to bombard a hydrogen rich target (used both...
  47. B

    How Raman Spectroscopy works?

    Hello, I am currently in an analytical chemistry course where I am required to write a report on Raman Spectroscopy. The typical description of Raman Spectroscopy is the excitation of an electron to a "virtual" state, whereupon it can relax to a non zero vibrational level in its ground...
  48. S

    Rutherford Backscattering Spectroscopy Question

    In class we learned about the fundamentals behind RBS using a linear accelerator that accelerates He+ ions to 2MeV. We were then provided an example where those ions collided with a sample with layers of Silicon-Bismuth-Silicon, each of known thickness; and, we were then shown the corresponding...
  49. J

    Question: Regarding Stellar Spectroscopy Equipment.

    Hi, I am new to this forum but I am an applied physics student and I'm working on a seminar on deep space spectroscopy. My question is actually on the equipment being used for my research. I am using an SBIG ST-7 camera with a DSS-7 spectrograph and I've been running calibration studies with...
  50. O

    How to report mass spectroscopy and elemental analysis in the RSC style

    Hi, I am currently in the process of writing up my lab reports and wanted to know how to report mass spectroscopy and elemental analysis in the RSC style. In my report guidelines it suggests elemental analysis should be reported as follows: "Shown in the form: Found: C, 63.1; H, 5.4...
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