Atomic Structure- Energy diff between levels

In summary, the conversation discusses calculating the energy difference between adjacent vibrational levels for the NaCl molecule using the given atomic weights, internuclear separation, and spring constant. The student attempted to use reduced mass and the equation for energy, but received an incorrect answer due to incorrect units. Additional constants were provided for reference.
  • #1
rxy152
9
0

Homework Statement


Consider the NaCl molecule, in which the atomic weights of Na and Cl are 23 and 37, respectively. The internuclear separation is 0.236 nm, and the ”spring constant” for vibrations is k = Mred ω^2 = 1 × 10^9 J/m^2 . Calculate the energy difference between adjacent vibrational levels. The value of h-bar is 1.055 × 10^−34 J · s. Answer in units of eV

Homework Equations

The Attempt at a Solution


I tried using reduced mass where m(red) = 23*37 / (23+37)= 14.18

Then plugged m(red) in the equation k = Mred ω^2 where i solved for ω = 8396

With ω, I used E=hbar * ω to get E = 8.8548E-31 J

= 5.527E-12 eV, which is wrong.

Plz Help!
 
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  • #2
Check your units. Are the masses of Na and Cl in kg?
 
  • #3
phyzguy said:
Check your units. Are the masses of Na and Cl in kg?

It doesn't state the units, which i thought was weird.

Here are some constants provided -
The value of h bar is 1.05457 × 10^−34 J · s ; the speed of light is 2.99799 × 10^8 m/s ; the value of h is 6.62607 × 10^−34 J · s ; the Rydberg constant for hydrogen is 1.09735 × 10^7 m −1 ; the Bohr radius is 5.29177 × 10^−11 m ; and the ground state energy for hydrogen 13.6057 eV .
 
  • #4
rxy152 said:
It doesn't state the units, which i thought was weird.

You need to look up what "atomic weight" means, and how to calculate the mass of an atom (in kg) given its atomic weight.
 

1. What is the concept of energy levels in atomic structure?

The concept of energy levels in atomic structure refers to the energy states that an electron can occupy within an atom. These energy levels are represented by different quantum numbers and are arranged in a hierarchical manner, with the lowest energy level being the closest to the nucleus and the highest energy level being the furthest away.

2. How does an electron transition between energy levels?

An electron can transition between energy levels by either absorbing or emitting a specific amount of energy in the form of a photon. This energy can come from an external source, such as heat or light, or from interactions with other particles within the atom.

3. What is the difference in energy between two adjacent energy levels?

The energy difference between two adjacent energy levels is known as the energy gap. This energy gap is specific to each atom and is determined by the atomic structure and the arrangement of electrons within the atom. The energy gap increases as the distance between energy levels increases.

4. Can an electron occupy multiple energy levels simultaneously?

No, an electron can only occupy one energy level at a time. This is due to the principle of energy conservation, which states that energy cannot be created or destroyed, only transferred. Therefore, an electron must either gain or lose energy to transition between energy levels.

5. How does the energy of an electron relate to its position in an atom?

The energy of an electron is directly related to its position within an atom. Electrons closer to the nucleus have lower energy levels, while those further away have higher energy levels. This is because the closer an electron is to the nucleus, the stronger the attractive force between them, resulting in a lower energy state.

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