Half-Reactions in Zn + HCl Reaction

In summary, the conversation discusses the concept of half-reactions and how they represent the transfer of electrons in oxidation and reduction reactions. The half reactions for the given equation are given for Zn and HCl, and it is noted that in the gas phase, only HCl is present and undergoes the reaction. The use of oxidation numbers as an accounting device for tracking electrons is also mentioned.
  • #1
Kaneki123
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I do not have a clear concept about half-reactions...Can someone please give the half reactions for following reaction,
Zn^0 + 2H^1 Cl^-1 -----> Zn^+2 Cl2^-1 + H2^0
or Zn + HCl ----> ZnCl2 + H2
 
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  • #2
"Half reaction" is used when you have to deal with oxidation/reduction reactions. Half reaction represents how electron is produced/consumed for reducing and oxidizing agent. So,
Zn = Zn2+ + 2e-
2HCl + 2e- = 2Cl- + H2
Add both equation and you will see.
 
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  • #3
HAYAO said:
"Half reaction" is used when you have to deal with oxidation/reduction reactions. Half reaction represents how electron is produced/consumed for reducing and oxidizing agent. So,
Zn = Zn2+ + 2e-
2HCl + 2e- = 2Cl- + H2
Add both equation and you will see.
Also one more thing...In the given equation, the oxidation state of H is changed...So would we say that H is being reduced or its whole compound HCl is being reduced?
 
  • #4
In water Cl- is just a spectator, it is H+ that reacts.

But in the gas phase, where only HCl is present I am ready to accept your statement as a correct. Pointing to an element in a compound and stating "this is what is being reduced/oxidized" is often questionable, as it is whole molecule/ion that undergoes the reaction. Yes, when we use oxidation numbers for redox reactions that how we think about the process, but oxidation numbers are just a accounting device designed for keeping track of electrons in the reaction. There is no property of an atom that we can measure to check its oxidation number.
 

1. What is the purpose of using half-reactions in the Zn + HCl reaction?

Half-reactions are used to represent the oxidation and reduction processes that occur in a redox reaction. In the case of Zn + HCl, zinc is oxidized to Zn2+ ions while hydrogen ions are reduced to form H2 gas. By separating the reaction into two half-reactions, it is easier to track the transfer of electrons and understand the overall redox process.

2. How do you determine which element is being oxidized and which is being reduced in the Zn + HCl reaction?

In a redox reaction, the element that loses electrons is being oxidized while the element that gains electrons is being reduced. In the Zn + HCl reaction, zinc (Zn) is losing electrons to form Zn2+ ions, making it the reducing agent. Hydrogen (H) is gaining electrons to form H2 gas, making it the oxidizing agent.

3. Can you write the half-reactions for the Zn + HCl reaction?

Yes, the half-reactions for the Zn + HCl reaction are:

Reduction half-reaction: 2H+ + 2e- → H2

Oxidation half-reaction: Zn → Zn2+ + 2e-

4. What is the role of the acid (HCl) in the Zn + HCl reaction?

The acid acts as a source of hydrogen ions (H+), which are necessary for the reduction half-reaction to occur. Without the acid, the reaction would not proceed as hydrogen ions are required to reduce the zinc ions.

5. How does the concentration of HCl affect the Zn + HCl reaction?

The concentration of HCl affects the reaction rate of the Zn + HCl reaction. A higher concentration of HCl means there are more hydrogen ions available to react with the zinc, leading to a faster reaction rate. However, once all the zinc has been consumed, increasing the HCl concentration will not affect the reaction as there are no more zinc ions to react with.

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