Na+ & OH- Dissociation: Energy Absorbed yet Heat Liberated

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Discussion Overview

The discussion revolves around the dissociation of Na+ and OH- ions, specifically addressing the apparent contradiction of energy absorption during dissociation and the liberation of heat in the overall process. The scope includes conceptual understanding and thermodynamic principles related to enthalpy and entropy.

Discussion Character

  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • One participant expresses confusion about how the dissociation of Na+ and OH- ions absorbs energy while the overall process liberates heat.
  • Another participant suggests that understanding the enthalpy of dissolution may clarify the situation, noting that breaking the lattice energy requires energy, but the solvation process can lead to an overall exothermic reaction.
  • It is mentioned that both enthalpic and entropic factors must be considered in this context.

Areas of Agreement / Disagreement

The discussion does not reach a consensus, as participants express differing levels of understanding and clarity regarding the thermodynamic principles involved.

Contextual Notes

Participants do not fully explore the assumptions underlying the concepts of enthalpy and entropy, nor do they detail the specific conditions of the reaction being discussed.

m0286
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Nevermind!

My heads going crazy when I think about this PLEASE HELP!

In a reaction, Na+ ions are separated from OH- ions, a process of dissociation that absorbs energy, yet, in the end, heat was liberated by the overall process... WHY? :bugeye:
 
Last edited:
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Never Mind I Figured It Out Thanks For Looking Though :)
 
It may still be instructive (to yourself) and others to post whatever it is that you have figured out.
 
enthalpy of dissolution heh? It takes energy to break apart the lattice energy, yet the increased order associated with the solvation suffices for the overall reaction to be exothermic. The one has to take into account both enthalpy and entropical factors.
 

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