Thermocouples operate by measuring the temperature difference between two dissimilar metals at different junctions. The introduction of copper extension wires creates additional junctions, leading to extra electromotive force (EMF) that can complicate temperature readings. Temperature controllers may not compensate for this additional EMF, affecting accuracy. Using extension or compensating cables made from materials similar to the thermocouple can mitigate this issue. Proper understanding of thermocouple principles is crucial for accurate temperature measurement.