I want to break this into two parts, because I don't want there to be any confusion about what I am questioning
Antiphon said:
It is precisely at this time and place, between slit and detector that the HUP is applicable.
Once we get to the point of analyzing the statistical data of many trials, this uncertainty will manifest itself in the measurements as precisely the statistical deviations which have been previously posted. But it would be wrong to conclude from this that the uncertainty is only expressed statistically and therefore applies only to an ensemble of many measurements.
This I agree with, and it is the central point I have been trying to make. The HUP applies to every
single particle that traverses the gap between the slit and the screen. The particle does not have a definite momentum in this region, and it cannot because it has been localized by the slit. HUP demands that the particle not be in a momentum eigenstate from the moment this localization takes place and at least until some future interaction.
Antiphon said:
The two views in dispute are not at odds after the experiment.
After the data is collected and analyzed it is meaningful to say as ZapperZ says the he has made accurate measurements of position and momentum, and its true that the momentum was conserved and that it was imparted to the particle by the slit.
But as I've mentioned above, in transit between the slit and screen, the momentum imparted by the slit is not "known" even to the slit until after the particle hits the detector. For this to be otherwise implies either a violation of conservation of momentum, or a purely classical trajectory.
This sounds too deterministic to me. How do you conserve that which you do not have? If the particle does not have a
definite momentum between the slit and the screen, how do we conclude that a second
position measurement retroactively puts the particle into a definite
momentum state? I am not disputing the idea of entanglement. If we really did manage to precisely measure the momentum of the particle, then I suppose the slit should exhibit a recoil to conserve system momentum, if the state of the slit had remained entangled with the particle. But the slit is such a complex system, with all kinds of interactions going on while the particle is traversing the gap that I suspect entanglement would have to be considered in the other direction. The slit is the thing that is going to interact first with something else and that interaction is likely to force it, and therefore the particle, into a definite state.
I don't really want to focus on this unless it is absolutely necessary to understand what happens to the particle. But it does make me wonder if the particle can be forced into a definite state by entanglement because of interactions of the slit with the rest of the universe. Instead I want to pursue the evolution of the state of the particle without ever again worrying about the momentum of the slit.
I understand why ZapperZ is uncomfortable with the idea that a position measurement cannot be used to infer momentum. I am not arguing that it is impossible to use position to discriminate momentum. I am arguing that the single slit experiment is not consistent with spatially based momentum discrimination. I also think single slit diffraction has nothing to do with the ARPES experiments, except perhaps as an ultimate limit on resolution that has not even been approached. I'm not sure I am going to get this exactly right on the first try, even if I am on the right track, but I'm going to throw it out there for discussion. The question I want to pursue is, under what conditions can position measurements be used to deduce momentum?
In the single slit scenario we are all assuming that before the slit confinement the particle is in a highly localized momentum state. We all still believe there is a connection between momentum and direction of motion, both classically and in QM. We agree that when the particle leaves the slit its momentum is spread because the slit has imparted unknown momentum to the particle. I would say that since QM says this momentum is not specific, but can be cast as a superposition of momentum eigenstates, that conservation of momentum demands that
each of these components be conserved. In other words, whatever linear combination of momentum eigenstates was prepared when the particle passed through the slit, it will have that same linear combination at all points in space and time between the slit and the screen.
The superposition of momentum eigenstates can be expressed as a wave packet that spreads spatially with time while conserving the individual momentum components. Any spatial detector (screen) that I put in front of this wave packet is going to detect a hit at some location with the probability of a hit at anyone location determined by the spatial probability density function of the particle. My question is, does this detection by the screen tell me that the particle followed a trajectory along a line from the slit to the screen, implying that the particle
had (or acquires retroactively) a particular momentum all the time? It sounds to me like you are saying it did, but that the path and its associated momentum did not exist until the second localization took place.
I have a hard time with that idea. If the particle had localized momentum between the slit and the screen it would not have been spatially localized to a linear path between them. If it were in a transverse momentum eigenstate, it would have had an infinitely broad transverse spatial probability distribution, which means I could have detected it hitting at any location on the screen. I don't think it is possible to conclude that the momentum vector of the particle points from the slit to the location of the screen detection based on two position measurements. This is why in an earlier post I questioned whether a momentum measurement had been made at all.
If you allow an ensemble of particles to pass through the slit you create a "beam". Classically, if the slit were imparting varying amounts of transverse momentum to the particles, each particle (assumed non-interacting) in the beam would be confined to one linear path within the beam. We could say that an arrival at a point on the screen limited the direction of arrival to a narrow wedge extending back from the point of arrival to the edges of the slit. In QM we cannot do that. The beam in QM is a spreading wave packet within which each particle is non-localized until it is position detected. When it is position detected by the screen, we cannot infer anything about where it might have been detected if the screen had been placed somewhere else, except to say it had to be somewhere in the beam. I will elaborate on this.
Suppose we did not know about the slit and we detected a hit on the screen. What would we know about the momentum of what hit the screen? Nothing more than perhaps which side of the screen it came from. If our screen had detectors that responded differently to particles of different energies, then we could say we know where the particle hit, and how much energy it had, so we could deduce the magnitude of the momentum, but we still would not have a measurement of the direction of arrival. Now the slit comes into the picture. If we can say that the particle came through the slit
and followed a straight line trajectory from the slit to the screen, then we can say we know the direction of the momentum. Classically we can surely do that, but can we do it in QM? I think not. There is nothing in QM that tells us how a particle makes its way form one position allowed by its wave function to another position.
To be more specific, let y be the transverse coordinate in a single slit experiment. One particle comes through a narrow slit centered at y = 0. At a distance L from the slit in the forward direction, say I detect the particle at y = a. Classically I can infer that if I had placed my screen at a distance L' from the slit then I would have detected that same particle at position y = a(L'/L). In QM, if I had placed the screen at some other location it might have detected the particle at
any y position permitted by its wave function. If you imagine that the particle actually had an "undetermined" position at distance L/2 of y = -a/2, it might still arrive at distance L with a position y = a. In fact, the particle could arrive at y = a at distance L from any prior location consistent with the evolution of its wave function. This leads me to conclude that the only way to measure the momentum of the particle when it hits the screen is to measure the
direction of arrival. I cannot do that in this single slit experiment with a position detector. If I have prepared a particle in such a way that it is in a state of superposition of momentum states and I detect its position without measuring its direction of arrival, then I can only conclude that it arrived with the distribution of momentum states included in the superposition. I have not selected anyone momentum state.
So how can I use a position measurement to measure momentum? I can do it by placing my detector in a position such that the only particles that it can possible detect are particles that have a narrow spectrum of momentum. For example, if instead of a single slit we had multiple slits we would create a very different situation. Although the individual slits are extremely narrow, we are not forcing a particle through anyone of them. The more slits the better because the more of them you have, the better you can associate the
possible subsequent positions of the particle with its momentum distribution. What you have accomplished is to create beams originating from the same aperture (not too narrow) all going in different directions. A beam is characterized by a width that is going to spread depending on its momentum spectrum. If you start with a large enough aperture, the momentum spectrum of a beam going in some direction can be very narrow.
This is what happens when you use a diffraction grating spectrometer to observe the emission spectra of an element like hydrogen. If you allow a beam of light from hydrogen gas discharge to pass through a huge number of extremely narrow slits, out comes a bunch of collimated beams traveling in different directions. The incoming beam is not monochromatic; it is really a spatial mixture of several different beams each characterized by a well defined momentum. At the grating, each beam has picked up a substantial transverse momentum, but with a corresponding change in the forward momentum to conserve energy (wavelength). More importantly, from a QM perspective each beam is a very slowly spreading wave packet with a very narrow momentum distribution permitted by the fact that the initial aperture, while small enough to produce a collimated beam, is not small enough to cause significant aperture spreading. If you make detections that are far enough away from the grating, you can infer the momentum quite accurately because the only way the particle could get to that detection location is by having a momentum in the very narrow spectrum of that beam. You have spatially separated the wave packets of particles of different energy and average momenta. You cannot say that detections on the left side of one beam have different momentum than detections on the right side of that beam. What you can say is that any detection associated with that beam has the momentum distribution characteristic of that collimated beam.
If instead of a gas discharge tube you use a white light source, you create a continuous spread of beams. No matter how far away you look back toward the grating, you will never completely separate the beams, but you do get better separation as you move farther away. With a small sensitive detector you can be quite selective about the range of momenta you permit to hit the detector, and you can improve the resolution by moving farther away.
Diffraction gratings are of course not the only things that can spatially separate overlapping beams. A beam of charged particles will interact with an electromagnetic field. Classically, a uniform magnetic field puts each charged particle into a circular trajectory whose radius depends on its momentum (its velocity), so half a circle away particles of the same mass with different energies are separated, or particles with the same velocity and different masses are separated. For each of them we can draw a circular trajectory back to the point of entry into the field. In QM, each of the momentum components of a beam will be affected by the field. If the incoming beam is a mix of particles with different momenta, and if we do not force them through a narrow aperture at entry that introduces significant spreading of their wave packets, then position measurements half a circle away can be used infer their momentum at entry into the field. Mass spectrometry of course relies on these final position measurements to infer momentum at field entry. But if at the point of entry you forced one particles through a narrow slit you would cause spreading of its wave packet in the field region and you would no longer be able to say that it followed a circular trajectory from the point of entry to the point where it hit the detector. Its evolution from the point of entry to the detector is known only as a position probability density. If I had detected the position of that same particle after an assumed 90 degree turn then I might have measured a very different circular path radius than the one I measured after an assumed 180 degree turn. If I forced it through a narrow slit, I cannot assume I know the direction it was heading when I detected it. Even classically you would be in trouble if you did not know with considerable certainty the direction of the particle at field entry because then you would not know where to locate the center of curvature of the classical trajectory. Hence the usual velocity selector at the front end of the mass spectrometer. The last thing I would want to do is introduce dispersion by using a too-narrow entrance slit.
I managed to find information about ARPES experiments and apparatus that I did not want to speculate too much about. First, if you want to explore the physics of the process of generating photoelectrons from a sample, this article is accessible online and goes into some detail about how you know the momentum components of photoelectrons transverse to a sample surface.
http://www.physics.ubc.ca/~quantmat/ARPES/PUBLICATIONS/Reviews/ARPES_intro.pdf
I make no pretense of having grasped that in detail, but I understand it sufficiently well to recognize that most of the calculations are based on the assumption that the photoelectrons are being emitted from the sample in momentum eigenstates. From a QM perspective that would imply infinite spatial non-locality. Of course the authors are implying no such thing. What they are really saying, in my interpretation, is that emanating from a small volume in the sample that is excited by incident photons is an electron that can be characterized by a wave function that corresponds to a wave packet of nearly constant momentum and sufficient spatial limitation so that as wave packets with different central momentum migrate away from the spot they will become spatially separated much the same way as white light would be separated by a grating. Figure 8 and the associated text gives a pretty good description of the physical arrangement. In particular I wanted to find out something about the nature and dimensions of a typical detector. That can be find here
http://www.gammadata.se/ULProductFiles/Scienta_R4000_1.pdf
The parameters of particular interest are:
The unique 0.1 mm wide slit
offers possibility of measuring extremely high energy resolution. and the typical electron energies in the range of 1 to 100 eV in their representative graphs for the angle resolution mode. The deBroglie wavelength of a 1eV electron is about 12nm, so we are talking about a slit that is on the order of 10,000 electron wavelengths or more. The other dimension of the slit is the one that would create momentum spreading in the direction of momentum resolution, and it is even wider, though not specified. In other words, single slit diffraction is not an issue. Once those electrons get out of the sample they are headed off into space with highly localized momentum that permits spatially separated detections to be associated with nearly unique momentum values.
So, at least for the moment, I am completely comfortable with ZapperZ believing that he is discriminating momentum in his experiments and finding useful information about the energy/momentum relationships in the materials he is studying, and I am comfortable that ARPES has nothing to do with the single slit experiment and its relationship to HUP. I am also still confident that in the single slit scenario a hit on the screen does not constitute a momentum measurement. My comfort may only last until the next message is posted, but so be it.