Pickling of steel in Hydrochloric Acid

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Using 15% hydrochloric acid effectively removes rust from mild steel, but can lead to rapid corrosion afterward due to chlorine residue on the surface. This chlorine can poison the iron, making it difficult to prevent future rusting, especially in marine environments or where road salt is used. An alternative rust removal method involves immersing items in molasses for a week, which is favored by tool and machinery re-builders. Additionally, commercial rust converters that apply a phosphate coating can help protect the steel surface. Proper post-treatment care is essential to mitigate corrosion risks after acid cleaning.
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I have some pieces of rusted mild steel pipes that i intend to remove rust from.I inserted a test sample in 15% Hydrochloric acid for 4 hours after which all the rust was removed from the surface and corrosion has slowed dramatically after washing off the acid.The subsequent pieces of steel pipe I tried on a large scale showed rapid corrosion soon after the pipes have been removed from the acid .What could be the cause of this
 
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Chlorine from the HCl remains on the steel surface and causes corrosion to return. Once an iron surface is poisoned with chlorine it is close to impossible to remove. It is a real problem in marine situations and causes car bodies to rust where salt is used on the road to prevent ice.

A slower process, that is often preferred by tool and machinery re-builders, is to immerse a rusty item in molasses for a week.
http://www.practicalmachinist.com/vb/general-archive/rust-removal-using-molasses-90452/

There are commercial rust converters that protect the surface with a phosphate.
 

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