Angular frequency of a matter patter

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By the de Broglie relations: E = \hbar * \omega

Is the angular frequency (\omega) in this equation an average or is it a constant? In other words, does the angular frequency (or the wavenumber, k) for a matter particle change, for instance, in differing gravitational fields, such as we see for a photon with gravitational redshift?
 
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I can restate the question in a related way.

Assume a spin-1/2 particle is described by a probability amplitude function (\Psi) with angular frequency (\omega) or wavenumber (k). The probability amplitude distribution for that particle exists within a volume of space-time. Assume that within that volume of space-time, there is an electromagnetic field that varies significantly in strength over that volume. How does that varying electromagnetic field affect the wavenumber/angular frequency of the particle's probability amplitude distribution?
 
Er... I have almost no clue on what you're getting at here.

Let's look at a less "exotic" example, shall we? Something that every single physics undergraduate does - tunneling through a square potential barrier. Look at the wave vector as it goes through the various regions. Does it change?

Zz.
 
Insights auto threads is broken atm, so I'm manually creating these for new Insight articles. Towards the end of the first lecture for the Qiskit Global Summer School 2025, Foundations of Quantum Mechanics, Olivia Lanes (Global Lead, Content and Education IBM) stated... Source: https://www.physicsforums.com/insights/quantum-entanglement-is-a-kinematic-fact-not-a-dynamical-effect/ by @RUTA
If we release an electron around a positively charged sphere, the initial state of electron is a linear combination of Hydrogen-like states. According to quantum mechanics, evolution of time would not change this initial state because the potential is time independent. However, classically we expect the electron to collide with the sphere. So, it seems that the quantum and classics predict different behaviours!
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