Van der Waals forces are generally stronger in water than in air due to the higher dielectric constant of liquids, which enhances molecular interactions. The discussion highlights that gas molecules experience weaker interactions compared to those in liquids, contributing to the distinct states of matter. The size of particles, such as silica, may appear larger in gas than in liquid, but this does not directly correlate with the strength of van der Waals forces. A smaller dielectric constant in gases reduces the shielding effect, allowing for stronger interactions at the molecular level. Understanding these forces is crucial for explaining the behavior of different states of matter.