To use ATX power connectors for devices, it's essential to understand the different connector footprints, such as 20-pin, 24-pin, and 4-pin configurations. The dimensions can be found in PC98 specifications, and it's crucial to check the power supply's datasheet for minimum output current requirements to ensure proper regulation. Without meeting these minimum loads, the power supply may not function correctly, especially in a lab setting. Connecting the PS_ON# pin to ground can activate the power supply, but testing output voltage is necessary for verification. Overall, careful consideration of specifications and load requirements is vital for effective use of ATX power supplies.