Average kinetic energy of the molecules in a cold liquid less?

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SUMMARY

The average kinetic energy of molecules in a cold liquid decreases as the temperature drops, directly correlating with the definition of temperature as a measure of average kinetic energy. This relationship is established through the kinetic theory, which states that temperature is proportional to the average kinetic energy of microscopic particles. However, the discussion highlights that temperature cannot solely be defined by kinetic energy, especially during phase transitions where energy distribution varies. The complexities of thermal equilibrium and the equipartition theorem further illustrate that temperature is a broader concept than just kinetic energy.

PREREQUISITES
  • Understanding of kinetic theory and its implications on temperature.
  • Familiarity with the concept of thermal equilibrium in thermodynamics.
  • Knowledge of phase transitions and their effects on energy distribution.
  • Basic principles of the equipartition theorem in statistical mechanics.
NEXT STEPS
  • Explore the kinetic theory of gases and its relation to temperature.
  • Study the laws of thermodynamics, particularly the 0th law regarding thermal equilibrium.
  • Investigate phase transitions and their thermodynamic implications.
  • Learn about the equipartition theorem and its applications in statistical mechanics.
USEFUL FOR

Students and professionals in physics, particularly those studying thermodynamics, molecular physics, and statistical mechanics, will benefit from this discussion.

  • #31
russ_watters said:
Agreed. DrClaude, what struck me as odd was your initial incredulity on the issue - as if you'd never heard of the connection.
What probably got me started was the use of the the word defined, with emphasis, in PWiz' original reply (and please don't take this personally, PWiz). Temperature has never been defined as such.

sophiecentaur said:
But that's the basis of the Kinetic theory that we all start with. It's only fair tp acknowledge that (albeit with a caveat or two). We discuss Newton's Laws of motion on PF, despite the fact that we know about Relativity.
I disagree with your analogy in that historically, temperature was never based on kinetic theory. All of classical thermodynamics and even parts of statistical physics were developed with scientists not even agreeing on the existence of molecules.

sophiecentaur said:
Anyway, i don't see a problem with using kinetic energy as an admittedly limited starting point. Then, you pull out the caveats as needed. To me, it is a lot better than using an empty/circular definition.
This entire thread has made me think a lot about how the concept of temperature is taught. I have myself used the simplification that temperature is motion, but I think that at the moment one reaches university level on the subject, this should be abandoned, as my feeling is that it leads to a wrong way of thinking. I have even revisited threads on PF, in particular Can a single atom have a temperature? I agree with Vanadium's answer and more or less disagree with Baluncore answer.

Anyway, my intentions were purely pedagogical, so I hope at least one person reading my posts will have learned something. I hope this didn't go over the head of the OP, and maybe it would be time to close the thread as we have most probably veered off course from the original question.
 
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  • #32
We had a minor run-in with "temperature" over on the latest "Ceres" thread. It was quite enlightening.

OmCheeto said:
This might be a counterexample to sophiecentaur's quote; "The enemy of understanding is classification."
Temperature in the ISM may need a different classification.
I learned long ago that temperature was defined as; "The average internal translational kinetic energy", or something like that.
For solids, liquids, and gasses, this kind of makes sense to me.
It's the average jigglinesss.

I think it started, with a comment about the temperature of outer space, which led me to an interesting thread: Coldness of Space

Where I found that Marcus had described "temperature" as a bunch of photons in a box.

Which, I'm quite sure, is true, also.
 
  • #33
DrClaude said:
so I hope at least one person reading my posts will have learned something.
I did. Thanks for sharing the knowledge!
DrClaude said:
and please don't take this personally, PWiz).
There is no "I" in objectivity; hopefully, I'll never take these things personally in the future too, because the day I do, I'll stop learning.
 

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