Average kinetic energy of the molecules in a cold liquid less?

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Discussion Overview

The discussion revolves around the relationship between temperature and the average kinetic energy of molecules in a cold liquid. Participants explore the definitions and implications of temperature, kinetic energy, and their interrelation, addressing both theoretical and conceptual aspects.

Discussion Character

  • Debate/contested
  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • Some participants assert that as the temperature of a liquid decreases, the average kinetic energy of its molecules also decreases, questioning the underlying reasons for this relationship.
  • Others challenge the definition of temperature as the average kinetic energy, suggesting that this definition may not hold in all contexts, such as in solids or during phase transitions.
  • A participant references the kinetic theory, noting its limitations and suggesting that temperature is more accurately defined through thermal equilibrium rather than solely through kinetic energy.
  • Some argue that temperature is what a thermometer measures, implying that this definition is more practical than a strict kinetic energy association.
  • Concerns are raised about the implications of defining temperature as average kinetic energy, particularly in scenarios like the triple point of a substance where different phases coexist at the same temperature.
  • There is a discussion on the equipartition theorem and how energy is distributed among different degrees of freedom, which may affect the understanding of temperature and energy exchange.
  • One participant emphasizes that temperature is not strictly related to kinetic energy outside of ideal gases, suggesting a broader interpretation of energy forms involved in temperature measurement.

Areas of Agreement / Disagreement

Participants express disagreement regarding the definition of temperature and its relationship to average kinetic energy. While some support the kinetic energy definition, others argue against it, leading to an unresolved discussion with multiple competing views.

Contextual Notes

Participants highlight limitations in definitions and assumptions, particularly regarding the applicability of kinetic energy definitions in various states of matter and during phase transitions. The discussion also reflects a lack of consensus on how temperature should be defined in relation to energy.

  • #31
russ_watters said:
Agreed. DrClaude, what struck me as odd was your initial incredulity on the issue - as if you'd never heard of the connection.
What probably got me started was the use of the the word defined, with emphasis, in PWiz' original reply (and please don't take this personally, PWiz). Temperature has never been defined as such.

sophiecentaur said:
But that's the basis of the Kinetic theory that we all start with. It's only fair tp acknowledge that (albeit with a caveat or two). We discuss Newton's Laws of motion on PF, despite the fact that we know about Relativity.
I disagree with your analogy in that historically, temperature was never based on kinetic theory. All of classical thermodynamics and even parts of statistical physics were developed with scientists not even agreeing on the existence of molecules.

sophiecentaur said:
Anyway, i don't see a problem with using kinetic energy as an admittedly limited starting point. Then, you pull out the caveats as needed. To me, it is a lot better than using an empty/circular definition.
This entire thread has made me think a lot about how the concept of temperature is taught. I have myself used the simplification that temperature is motion, but I think that at the moment one reaches university level on the subject, this should be abandoned, as my feeling is that it leads to a wrong way of thinking. I have even revisited threads on PF, in particular Can a single atom have a temperature? I agree with Vanadium's answer and more or less disagree with Baluncore answer.

Anyway, my intentions were purely pedagogical, so I hope at least one person reading my posts will have learned something. I hope this didn't go over the head of the OP, and maybe it would be time to close the thread as we have most probably veered off course from the original question.
 
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  • #32
We had a minor run-in with "temperature" over on the latest "Ceres" thread. It was quite enlightening.

OmCheeto said:
This might be a counterexample to sophiecentaur's quote; "The enemy of understanding is classification."
Temperature in the ISM may need a different classification.
I learned long ago that temperature was defined as; "The average internal translational kinetic energy", or something like that.
For solids, liquids, and gasses, this kind of makes sense to me.
It's the average jigglinesss.

I think it started, with a comment about the temperature of outer space, which led me to an interesting thread: Coldness of Space

Where I found that Marcus had described "temperature" as a bunch of photons in a box.

Which, I'm quite sure, is true, also.
 
  • #33
DrClaude said:
so I hope at least one person reading my posts will have learned something.
I did. Thanks for sharing the knowledge!
DrClaude said:
and please don't take this personally, PWiz).
There is no "I" in objectivity; hopefully, I'll never take these things personally in the future too, because the day I do, I'll stop learning.
 

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