Behavioural characteristics of Titanium & Graphite

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The discussion focuses on the tribological performance of titanium and graphite in high-temperature environments, particularly concerning friction and wear over time. It highlights that graphite requires minimal moisture to maintain its lubricity; in dry or high-temperature conditions, it can become abrasive. Historical references indicate that graphite brushes in electric motors experienced wear issues at high altitudes due to dry air. Concerns are raised about the potential for graphite to damage titanium's protective TiO2 layer, leading to increased oxidation and the formation of titanium carbide (TiC) at elevated temperatures. The effectiveness of titanium and graphite as a pairing is influenced by factors such as speed, load, temperature, and the composition of the surrounding atmosphere. Alternative high-temperature lubricants, such as copper-based options, are suggested for improved performance.
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Hi all,

Does anybody have any experience with titanium and graphite in terms of friction and wear over time in a relatively high temperature environment?
I realize that galvanic corrosion shouldn't be too much of an issue, but I was wondering from a sort of tribological point of view.
Hope this makes sense
Thanks in advance
 
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AB_type_S said:
Hi all,

Does anybody have any experience with titanium and graphite in terms of friction and wear over time in a relatively high temperature environment?
I realize that galvanic corrosion shouldn't be too much of an issue, but I was wondering from a sort of tribological point of view.
Hope this makes sense
Thanks in advance

Graphite depends on having minuscule amounts of water in its environment to maintain its lubricity. In a very dry environment or one hot enough to drive off intercalated water, it becomes quite abrasive. This was first found, IIRC, in WWII when graphite brushes in electric motors flown at then-novel high altitudes ( = very dry air) started chewing into the commutator metal.

Titanium against graphite at high temperatures is likely to wear fairly fast. I speculate the graphite will damage the native TiO2 layer, which will expose underlying Ti to further oxidation and to reaction with the graphite. Ti forms TiC fairly readily at elevated temperatures. There are copper-based high temperature lubricants that might work for you.

The tribological performance of Ti/graphite depends on speeds, loads, etc. as well as temperature and atmosphere composition. If the environment is other than air, my comment is not likely to apply.
 
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