Absolutely there is a velocity profile across the jet. It peaks at the center and then smoothly drops to zero at the edges as you reach the ambient air. For a 2D, laminar jet, it is proportional to ##\mathrm{sech}^2(y)## if ##y## is the coordinate across a cross-section of the jet (assuming the jet leaves the nozzle at ambient pressure, which is usually the case).
The problem with using Bernoulli is that the entire reason the profile exists is due to viscosity. The shear layer that is set up at the edge of the jet entrains some ambient fluid while slowing down the edges of the jet, causing the whole system to slow and spread out. It's also subject to vortical instabilities (see: Kelvin-Helmholtz instability), and is just generally a poor candidate for applying Bernoulli. In fact, it is usually assumed that the pressure is constant across a jet and the same as ambient for an incompressible flow, much like a boundary layer. Similarly, we don't generally apply Bernoulli's equation to boundary layers.
I am not even convinced that it would work near the axis since the centerline flow is slowing with distance from the nozzle, yet the pressure is not generally changing. If you assumed that the ball in the jet is small compared to the axial distance over which the velocity in the undisturbed jet changes, then you could locally apply Bernoulli along a single streamline as it moves around the ball, but that's about it, and it would only be approximate.
In my description, I neglected any spin imparted on the ball, but the direction of spin would be correctly-predicted by what I said. The faster flow near the center being bent around the ball would also tend to rotate it such that the side closest to the centerline is moving along with the flow. The other side would be against the flow.