Bloch theorem proof with V(x)=V(x+ma)

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SUMMARY

The discussion focuses on the proof of Bloch's theorem using the potential function V(x) defined as V(x) = V(x + ma). The derivation involves applying the Hamiltonian operator H to the plane wave function W_k(x) and demonstrating that the resulting expression belongs to the subspace S_k of plane waves with wavenumbers k + h_n. The key equations referenced include the time-independent Schrödinger equation and the representation of the potential as a Fourier series. The participants clarify the validity of substituting W_k(x) into the equations, ultimately confirming the relationship holds true.

PREREQUISITES
  • Understanding of quantum mechanics, specifically the time-independent Schrödinger equation.
  • Familiarity with Bloch's theorem and its implications in solid state physics.
  • Knowledge of Fourier series and their application in representing periodic functions.
  • Basic concepts of wave functions and their properties in quantum mechanics.
NEXT STEPS
  • Study the derivation of Bloch's theorem in detail, focusing on the implications of periodic potentials.
  • Learn about the application of Fourier series in quantum mechanics, particularly in solid state physics.
  • Explore the Hamiltonian operator and its role in quantum mechanics, including its application to wave functions.
  • Investigate the properties of plane waves and their significance in the context of quantum mechanics.
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Students and researchers in physics, particularly those specializing in solid state physics, quantum mechanics, and mathematical methods in physics. This discussion is beneficial for anyone seeking to understand the application of Bloch's theorem and the behavior of wave functions in periodic potentials.

Philethan
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In Grosso's Solid State Physics, chapter 1, page 2, The author said that:

$$-\frac{\hbar^2}{2m}\frac{d^2\psi(x)}{dx^2}+V(x)\:\psi(x)=E\:\psi(x)\tag{1}$$

$$V(x)=V(x+ma)\tag{2}$$

$$V(x)=\sum_{-\infty}^{+\infty}V_n\:e^{ih_nx},\tag{3}$$where ##h_n=n\cdot2\pi/a##.

$$W_k(x)=\frac{1}{\sqrt{L}}e^{ikx}\tag{4}$$

If we apply the operator ##H=(p^{2}/2m)+V(x)## to the plane wave ##W_{k}(x)##, we see that ##H\left|W_{k}(x)\right\rangle## belongs to the subspace ##\mathbf{S}_{k}## of plane waves of wavenumbers ##k+h_{n}##:
$$\mathbf{S}_{k}\equiv\left\{W_k(x),W_{k+h_1}(x),W_{k-h_1}(x),W_{k+h_2}(x),W_{k-h_2}(x),\cdots\right\}$$

Therefore, I plug (4) into (1), and I expect that I can get the following relationship, which proves that ##H\left|W_{k}(x)\right\rangle## belongs to the subspace ##\mathbf{S}_{k}## of plane waves of wavenumbers ##k+h_{n}##:
$$\left[ -\frac{\hbar^2}{2m}\frac{d^2}{dx^2}+V(x) \right]W_k(x)\propto W_{k+h_n}(x)=\frac{1}{\sqrt{L}}e^{i(k+h_n)x}$$
Here's my derivation:
$$\begin{align}\left[ -\frac{\hbar^2}{2m}\frac{d^2}{dx^2}+V(x) \right]W_k(x)&=\left[ -\frac{\hbar^2}{2m}\frac{d^2}{dx^2}+V(x) \right]\frac{1}{\sqrt{L}}e^{ikx}\\[4ex]&=\frac{\hbar^2k^2}{2m}\left(\frac{1}{\sqrt{L}}e^{ikx}\right)+\sum_{-\infty}^{+\infty}V_ne^{ih_nx}\left(\frac{1}{\sqrt{L}}e^{ikx}\right)\\[4ex]&=\frac{\hbar^2k^2}{2m}\left(\frac{1}{\sqrt{L}}e^{ikx}\right)+\sum_{-\infty}^{+\infty}V_ne^{ih_n(x+ma)}\left(\frac{1}{\sqrt{L}}e^{ikx}\right)\\[4ex]&=\frac{\hbar^2k^2}{2m}\left(\frac{1}{\sqrt{L}}e^{ikx}\right)+\sum_{-\infty}^{+\infty}V_ne^{ih_n}\left(\frac{1}{\sqrt{L}}e^{i(kx+h_nma)}\right)\end{align}$$
Then, I just don't know how to do now. I have no idea how to simply and rewrite this result to prove that it really is proportional to ##W_{k+h_n}(x)=e^{i(k+h_n)x}/\sqrt{L}##. Could you please help me? I'll really appreciate that.
 
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Hmmm, the author says "in free-electron case ##V(x)=0##, the wavefunctions are simply plane waves and can be written in the form ##W_{k}(x)=\frac{1}{\sqrt{L}}e^{ikx}##".
Then he talks about periodic potential case. I'm not sure, but do you think that substitute ##W_{k}(x)## in (4) into (1) is correct? Because formula (4) is for free-electron case :confused:
 
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Nguyen Son said:
Hmmm, the author says "in free-electron case ##V(x)=0##, the wavefunctions are simply plane waves and can be written in the form ##W_{k}(x)=\frac{1}{\sqrt{L}}e^{ikx}##".
Then he talks about periodic potential case. I'm not sure, but do you think that substitute ##W_{k}(x)## in (4) into (1) is correct? Because formula (4) is for free-electron case :confused:
Well... Hmm... I'm not sure, but he also said "the plane waves (4) constitute a complete set of orthonormal functions, that can be conveniently used as an expansion set." Does that mean substitute ##W_{k}(x)## into (1) is correct? =0=
 
Wait a minute... suppose that we can use formula (4) for this case and put into (1), it's really simple
\begin{align}
\frac{-\hbar^{2}}{2m} \nabla^2 W_{k}(x)+V(x)W_{k}(x)&=\frac{-\hbar^{2}}{2m} \nabla^2 \frac{1}{\sqrt{L}}e^{ikx}+ \sum_{n=-\infty}^\infty V(h_{n})e^{ih_{n}x}\frac{1}{\sqrt{L}}e^{ikx}
\nonumber \\
&=\frac{\hbar^{2}k^{2}}{2m} W_{k}(x) + \sum_{n=-\infty}^\infty V(h_{n})\frac{1}{\sqrt{L}}e^{i(k+h_{n})x}
\nonumber \\
&=\frac{\hbar^{2}k^{2}}{2m} W_{k}(x) + \sum_{n=-\infty}^\infty V(h_{n})W_{k+h_{n}}(x)
\nonumber
\end{align}
So it's belong to that subspace ##S_{k}## above
 
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Oh! Haha. I'm so stupid that I didn't see it. Thank you so much! I understand it now :D
 
Oh you're welcome but don't say you're stupid. I think it's a conventional situation when we prove a formula/relation, we usually want to expand everything, substitute everything from everywhere to see the expected result at the end of the progression, but the result goes too far away that we couldn't see the relation :biggrin::biggrin::biggrin:
 
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