Calculate Change in Energy for n=4 to n=1 Hydrogen Atom

  • Thread starter Thread starter xmflea
  • Start date Start date
  • Tags Tags
    Chem
Click For Summary
SUMMARY

The discussion centers on calculating the change in energy for a hydrogen atom transitioning from n=4 to n=1 using the formula E = -Rh/n². The correct approach involves taking the difference between the inverse squares of the principal quantum numbers, specifically 1/n(low)² - 1/n(high)², and multiplying by the Rydberg constant (Rh). The final result for this transition is -2.04E-18 J, indicating that energy is released during the transition, which is consistent with the principle that energy lost by the atom is gained by the surroundings.

PREREQUISITES
  • Understanding of quantum mechanics and atomic structure
  • Familiarity with the Rydberg formula for hydrogen
  • Knowledge of energy transitions in atomic physics
  • Basic algebra for manipulating equations
NEXT STEPS
  • Study the Rydberg formula in detail for other transitions in hydrogen
  • Learn about energy levels and transitions in other elements
  • Explore the concept of energy conservation in quantum mechanics
  • Investigate the implications of energy sign conventions in physics
USEFUL FOR

Students of physics, educators teaching atomic theory, and anyone interested in quantum mechanics and energy transitions in atoms.

xmflea
Messages
43
Reaction score
0
Calculate the change in energy when the following transition occurs in the hydrogen atom.

n = 4 ----> n = 1

equation

E = -Rh/n^2

eventually my answer is 2.04E-18J because my book tells me to take 1 over n(low) squared minus 1over n(high) squared and multiply by rydberg constant.. so doing it according to the book i get a positive number

but the answer is -2.04E-18J... and now after looking online... I am getting serveral mixed sources, some saying that it is positive, others saying it is negative.. which is it.
 
Physics news on Phys.org
Negative.
 
This is change in energy. Whatever atom loses is gained by surroundings, so sign if the change is either negative or positive, depending on the point of view.

--
 

Similar threads

  • · Replies 3 ·
Replies
3
Views
4K
  • · Replies 2 ·
Replies
2
Views
2K
  • Sticky
  • · Replies 2 ·
Replies
2
Views
10K
  • · Replies 17 ·
Replies
17
Views
2K
  • · Replies 0 ·
Replies
0
Views
3K
  • · Replies 2 ·
Replies
2
Views
2K
Replies
1
Views
2K
  • · Replies 6 ·
Replies
6
Views
2K
Replies
9
Views
3K
  • · Replies 2 ·
Replies
2
Views
1K