Calculate the change in enthelpy

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In summary, the conversation discusses how to solve a problem involving the change in enthalpy and entropy when heating 1 mole of SiC from 25 degrees C to 1000 degrees C. It also mentions the equation for calculating entropy with temperature, as well as the role of constant pressure and non-expansion work in the problem. The question is identified as being under constant pressure based on the given Cp value, and non-expansion work is assumed to not be present unless stated otherwise.
  • #1
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how do you solve the following problem?

calculate the change in enthalpy and the change in entropy when 1 mole of SiC is heated from 25 degrees C to 1000 degrees C.
Cp=50.79+1.97*(10^-3)T-4.92*(10^6)(T^-2)+8.2*(10^8)(T^-3) J/(mole*K)
 
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  • #2
The variation of Entropy with temperature for a system is given by
[tex] S(T_f) = S(T_i) + \int \frac{dq_{rev}}{T} [/tex]
When the system is under constant pressure and there is no non-expansion work,
[tex] dq_{rev} = C_p dT [/tex]
 
  • #3
how do you know that the question is under constant pressure?
 
  • #4
because they give u Cp, which is the specific heat at constant pressure
 
  • #5
@@
how do you know that there's no non-expansion?
 
  • #6
Non expansion work is work done by the system other than in expansion.
For example, electrical work. So unless it is specifically stated, there is usually no non-expansion work.
 
  • #7
thank you very much!
 

1. What is enthalpy and why is it important?

Enthalpy is a measure of the total energy of a thermodynamic system, including both its internal energy and the work required to create or destroy the system. It is important because it helps us understand and predict the behavior of chemical reactions and physical processes.

2. How do you calculate the change in enthalpy?

The change in enthalpy is calculated using the formula ∆H = Hfinal - Hinitial, where H represents the enthalpy of the system at a specific temperature and pressure.

3. What units are used to measure enthalpy?

Enthalpy is typically measured in joules (J) or kilojoules (kJ) in the SI system of units. It can also be measured in calories (cal) in the older cgs system of units.

4. How does the change in enthalpy relate to the heat of a reaction?

The change in enthalpy is also known as the heat of reaction, as it represents the amount of heat that is either absorbed or released during a chemical reaction. A positive ∆H indicates an endothermic reaction, meaning heat is absorbed, while a negative ∆H indicates an exothermic reaction, meaning heat is released.

5. What factors can affect the change in enthalpy of a system?

The change in enthalpy can be affected by various factors such as temperature, pressure, concentration, and the physical state of the reactants and products. It can also be influenced by the presence of a catalyst or any changes in the number of moles of reactants and products.

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