A sphere cannot have a critical angle in the same way as a flat surface, as critical angles are specific to the geometry of the interface between two media. In the case of a water droplet, light undergoes refraction twice: once upon entering and again upon exiting, leading to the phenomenon of total internal reflection. The angle of refraction varies with the wavelength of light, causing different colors to refract at different angles. This process is similar to how a prism operates, resulting in the formation of a rainbow. Understanding these principles clarifies the optical behavior of light in spherical droplets.