Can Urochrome be Cracked into Individual Pyrroles?

  • Thread starter Thread starter JeffEvarts
  • Start date Start date
  • Tags Tags
    degradation
AI Thread Summary
Urochrome, a tetrapyrrole with methylene bridges connecting its pyrrole units, raises questions about potential methods for "cracking" the molecule to yield individual pyrroles. The discussion centers on the feasibility of breaking down urochrome in a manner similar to hydrocarbon cracking. One participant expresses skepticism about the simplicity of such a process, suggesting that it may be as complex as pyrrole synthesis itself. The inquiry highlights the abundance of urochrome and its relevance to pyrrole synthesis, prompting further exploration of possible methods for its breakdown.
JeffEvarts
Messages
74
Reaction score
7
Urochrome/urobilin (structure below) is a tetrapyrrole, with the pyrroles connected with methylene (ish) bridges. I'm wondering if there's a good way to "crack" this molecule (like a hydrocarbon) along the bridges to yield the individual pyrroles. I ask because pyrrole synthesis is involved, and urochrome is abundant.

-Jeff
726px-I-Urobilin-neutral.svg.png
 

Attachments

  • 726px-I-Urobilin-neutral.svg.png
    726px-I-Urobilin-neutral.svg.png
    8.1 KB · Views: 391
Chemistry news on Phys.org
I'm skeptical that any cracking pathway of these heme breakdown products is going to be less involved than pyrrole synthesis.
 
And I didn't say it WOULD be. I'm just posing the question.
 
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
I'm trying to find a cheap DIY method to etch holes of various shapes through 0.3mm Aluminium sheet using 5-10% Sodium Hydroxide. The idea is to apply a resist to the Aluminium then selectively ablate it off using a diode laser cutter and then dissolve away the Aluminium using Sodium Hydroxide. By cheap I mean resists costing say £20 in small quantities. The Internet has suggested various resists to try including... Enamel paint (only survived seconds in the NaOH!) Acrylic paint (only...
Back
Top