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ChmDudeCB said:Exactly. What we call "frozen water" isn't the only solid form of water, it's just the crystal structure that happens to form at atmospheric pressure. If you compress anything below its supercritical temperature it will eventually become solid (or a glass).
However, are you sure your phase diagram is accurate? IIRC once you pass the supercritical points of temperature and pressure, that is all that exists. I could be wrong and/or my P-chem professor left something out.
The supercritical point is just a point where the line of first order transitions between liquid and vapor ends. The critical point itself is point where there is a second order transition. There the heat capacity diverges with a certain universal critical exponent.
But this has nothing to do with the other phase transitions in the phase diagram.