The cathode end of a cathode ray tube is termed "cathode" because it emits electrons, which results in a positive charge due to the loss of negatively charged particles. This process is explained by thermionic emission, where heated electrons gain enough energy to escape from the filament's surface. The anode, conversely, is the receiving end that attracts these electrons, thus becoming more negatively charged. The discussion also touches on the notion that the naming conventions in physics may not always align with intuitive understandings of charge and potential. Ultimately, grasping the underlying principles is more important than the terminology used.