Change in internal energy of an ideal gas

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SUMMARY

The change in internal energy (ΔU) of an ideal gas can be expressed as ΔU = Δ(3/2)PV, confirming that knowing Δ(PV) allows for the determination of ΔU. This relationship is particularly useful when analyzing P-V diagrams. For closed systems, the equation ΔU = (3/2)NkT ΔT highlights that only temperature changes affect internal energy. Additionally, the first law of thermodynamics, ΔU = Q + W, remains essential for calculating energy changes in various thermodynamic processes.

PREREQUISITES
  • Understanding of the ideal gas law
  • Familiarity with thermodynamic concepts such as internal energy
  • Knowledge of the first law of thermodynamics
  • Ability to interpret P-V diagrams
NEXT STEPS
  • Study the ideal gas law and its applications in thermodynamics
  • Learn about isothermal processes and their implications for internal energy
  • Explore the derivation and applications of the first law of thermodynamics
  • Investigate the relationship between temperature, pressure, and volume in ideal gases
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Students and professionals in physics, engineering, and thermodynamics, particularly those focusing on the behavior of ideal gases and energy transformations in closed systems.

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Given that U = (3/2)PV does this mean that ΔU = Δ(3/2)PV for an ideal gas? Hence when finding the change in internal energy using a P-V diagram, can we simply apply this equation instead of using ΔU = Q+W?
 
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Yes, if you can know ##\Delta(PV)## you can know the change in internal energy. For this formula, you have to know both the initial and final pressure and volume. A more often seen version of this concept is using the other side of the ideal gas law, so that with constant N:

$$\Delta U = \frac{3}{2}Nk_T \Delta T$$

Thus, for a closed system, only a change in temperature will lead to a change in energy. Specifically, isothermal processes on ideal gases have the condition ##\Delta U =0##.

But ##\Delta U=Q+W## is the first law of Thermodynamics. It can come in very useful when you're finding either ##\Delta U## or ##Q## or ##W##. Often you will have to use this law in some form or another in many problems.
 
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