Change in thermal energy and Temperature problem

AI Thread Summary
The discussion revolves around calculating the change in internal energy (ΔU) and final temperature (Tf) for 1 mole of an ideal diatomic gas compressed adiabatically to 89.7% of its initial volume, starting at 22.5°C and 16.1 L. The user initially assumes ΔU equals work (w) due to the adiabatic nature of the process and calculates w using the ideal gas constant and volume ratios, arriving at 267.175 J. They then manipulate the internal energy equation to find Tf but receive an incorrect result. The user questions whether the equation for work applies to adiabatic processes and seeks clarification on the relationship between change in temperature and thermal energy. The conversation highlights the complexities of applying thermodynamic equations in adiabatic conditions.
laser123
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Homework Statement


Compute the change in internal energy, ΔU, and the final temperature, Tf, when 1 mole of an ideal, diatomic gas is compressed adiabatically to 89.700% of its initial volume. The starting point is 22.500°C and 16.100 L. (Assume that the vibrational degree of freedom stays inactive during the process.)

Homework Equations


eq. 1. W=NkTln(Vi/Vf)

eq. 2. Δu=Q+W

eq. 3. u=(f/2)NkT

The Attempt at a Solution



Okay since it's adiabatic I made the assumption Δu=w. So i used the abouve equation and solved for w=(6.02)(1.381)ln(16.1/14.447)=267.175 J

So i manipulate eq 3 and get u=(f/2)Nk(Tf-Ti) and (2u)/fNk+Ti=Tf=12.8548+295.65=308.505K. This the computer says is wrong?

Because when i find the change in Temp i plan on using du=(f/2)NkdT for the change in thermal energy
 
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laser123 said:
eq. 1. W=NkTln(Vi/Vf)
Does this equation hold for an adiabatic process?

when i find the change in Temp i plan on using du=(f/2)NkdT for the change in thermal energy

Sounds good.
 
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