Chemical attack of amorphous carbon

Click For Summary
SUMMARY

The discussion centers on the challenges of chemically attacking amorphous carbon films, commonly used as hard masks in nanolithography. Users highlight that while oxygen plasma is an effective method for removing amorphous carbon, it can be time-consuming and requires specific equipment like an asher. The possibility of using chemical solvents, such as Piranha solution, is considered, but experts indicate that complete dissociation of amorphous carbon chemically is nearly impossible. Safety precautions, including the use of a fume hood and personal protective gear, are emphasized for any chemical handling.

PREREQUISITES
  • Understanding of amorphous carbon properties and applications in nanolithography
  • Familiarity with oxygen plasma etching techniques and equipment
  • Knowledge of chemical solvents and their effects on carbon materials
  • Safety protocols for handling hazardous chemicals in a laboratory environment
NEXT STEPS
  • Research the effectiveness of Piranha solution on amorphous carbon films
  • Learn about alternative plasma etching methods for carbon removal
  • Investigate the operational parameters of oxygen plasma ashers
  • Explore safety measures and best practices for chemical handling in cleanroom settings
USEFUL FOR

This discussion is beneficial for materials scientists, cleanroom technicians, and researchers involved in nanolithography and carbon film processing.

physicist888
Messages
63
Reaction score
0
Hi everyone,
i wonder if anyone has an idea how to attack chemically an amorphous carbon film. Is it possible to completely dissociate an amorphous carbon in a chemical solvent?
thanks for your help
 
Physics news on Phys.org
a-carbon is often used as a hard mask in e.g. nanolithography but as far as I know it is then always removed using oxygen plasma (that is what I always used back when I was actually doing some cleanroom work); do you have access to an asher?
 
Actually it's well known that plasma oxygen attack will remove the a-Carbon. Such expermint take so long, its hard a little, and actually i don't have access to it all the time. that's why i thought that maybe i can etch the a-Carbon chemical attack, by a solvant (acid, base)... don't know
 
Piranha solution might work. A fume hood and personal protective gear (face mask, nitrile gloves, apron) are absolutely required.
 
I asked a colleague who has got a lot of experience with films of a-carbon, he tells me that it is almost impossible to remove them chemically.

Why does it take you so long when using oxygen plasma? As far as I remember it only took a few minutes to completely remove all carbon in plasma.
Of course there is also of pump-down time of the system etc but that shouldn't be very long for an asher, you do not need very low pressures for this.
 

Similar threads

  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 5 ·
Replies
5
Views
3K
Replies
2
Views
681
  • · Replies 3 ·
Replies
3
Views
6K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 7 ·
Replies
7
Views
7K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 5 ·
Replies
5
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 6 ·
Replies
6
Views
4K