At a surface boundary, you get polarization surface polarization charge density ## \sigma_p= \vec{P} \cdot \hat{n} ## where ## \hat{n} ## is the outward pointing unit vector normal to the surface. This is a result of the equation ## -\nabla \cdot P=\rho_p ## for polarization charge density. The surface charge density that arises depends on P which depends on the internal E and the surface charges that arise can affect the internal E. Yes, it is a self-consistent mathematics that is needed to solve this. For some simple geometries, ( in cases where you get a uniform ## P ## from a uniform applied field ##E_o ##), ## E_i=E_o-(C)(P)/\epsilon_o ## where ## E_o ## is the applied field and ## E_i ## is the field in the material, with C being a factor that depends upon the geometry. Since ## P=\chi \epsilon_o E_i ##, (using mks units), ## E_i ## can be found in terms of ## E_o ## and ## \chi ##, (simple algebraic solution), if the geometric factor C is known. For a plane slab C=1, and for a sphere C=1/3. (Not sure what letter the textbooks use for this factor C in electrostatics. For the analogous problem in magnetostatics, they usually use the letter D.) And note to prove the 1/3 factor for a sphere requires some rather complex mathematics involving Legendre Polynomials. It's a very useful result for problems involving dielectric spheres. The plane slab factor (C=1) is much more readily computed and can be calculated by using Gauss's law. For the plane slab, ## E_i=E_o/(1+\chi) ## which is essentially a screening factor of the electric field inside the material given by the normalized dielectric constant ## \epsilon/\epsilon_o =1+\chi ##. ..editing... to understand these concepts in more detail, I would suggest working the problem of the case of fixed uniform polarization ## P ## of on a material that occurs spontaneously without any externally applied field ## E_o ## . You can do this for a plane slab or for a sphere. Compute the electric field that arises in the material as a result of the surface polarization charge from the polarization ## P ##. (The polarization ## P ## has no local effect of the electric field at that point. The only sources of electric field is the surface polarization charge density that arises at the boundaries. And assume in this case the the electric field that arises does not affect the polarization ## P ##. This is a simpler case than that of a material that has ## P=\epsilon_o \chi E ## , but a good one to illustrate the concept of surface polarization charge.)