B CO2 Expansion: Will Temperature Fall Below 0C?

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The discussion revolves around the thermodynamic properties of CO2 as it expands from 47.3 bar to 34.85 bar, with a focus on enthalpy and entropy changes. It is established that the final temperature will be 0°C, with a mixture of approximately 90% vapor and 10% liquid. The calculation of entropy changes is debated, with a consensus that entropy should increase during the process, contradicting initial calculations suggesting a decrease. The importance of consistent units for enthalpy and entropy is emphasized, and the use of pressure-enthalpy diagrams is recommended for better understanding. The final entropy of mixed gases is confirmed to be higher than the original entropies of the individual gases involved.
  • #31
As a beginner I think I've reached the limit of my understanding thermodynamics and its accompanying math.I think its now time to study the required math and perhaps
we can resume this conversation.Thanks for your time and patience.
 
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  • #32
I'd like to make a suggestion. I think it would be very helpful for you to get some practice solving lots of simple problems involving entropy, such as with reversible and irreversible expnasions and compresions of ideal gases and heating/cooling of solids. This should give you a much better feel for how this all plays out.

Chet
 
  • #33
Thanks again for your help.
 
  • #34
You need to assign units to all your quantities.
 
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  • #35
Khashishi said:
You need to assign units to all your quantities.
This is a very valid point that rancam needs to pay much more attention to. I was able to decipher the units in post #7, but it would certainly have been much more desirable to carry units through all the posts.

Chet
 

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