smallphi said:
A system of oscillators like bunch of particles in quadratic potential would have unique ground state because you can solve for the wave function in an already defined Hilbert space spanned by eigenstates of the position or momentum operators.
On the other hand, the EM field is also a 'bose gas' but the Hilbert space is not spanned in advance before you postulate the existence and uniqueness of the ground state. The Hamiltonian may look like bunch of 'oscillators' but you are missing the formal expressions of the creation and annihilation operators in terms of differential operators acting in some functional space like in the case of harmonic oscillator. Hence you can't solve for the ground state of each 'oscillator' and prove its unique. The only way would be to postulate it and see if that agrees with experiment.
This threat is way to abstract and mixing up all kinds of things.
So, let’s try to handle this as
simple as possible:
1) Canonical ('second') quantization is not a quantization of the wave-
function in space but that of phi(x,t) as an internal coordinate.
2) The form of the wave-function in space is always assumed to be a
sinusoidal plane wave.
3) Second quantization is intended to be an explanation why the vacuum
can only have 1, 2, 3, ... n of such sinusoidal plane waves, for each
frequency, representing 1, 2, 3, ...n particles of that frequency.
CANONICAL QUANTIZATION OF THE KLEIN GORDON FIELD
==========================================
Now we get to our harmonic oscillators. You can literally see them
immediately by looking at this picture:
http://chip-architect.com/physics/Klein_Gordon.jpg
This is a mechanical representation (with springs and masses) of the
one dimensional real Klein Gordon equation:
\frac{\partial^2 \psi}{\partial t^2}\ =\ c^2\frac{\partial^2 \psi}{\partial x^2} - m^2 \psi
Where the horizontal axis is x and the vertical axis is psi. The wave-
functions of this mechanical system behave exactly as deBroglie waves,
including the phase speed of c^2/v.
The vertical springs c^2 determine the propagation speed and the
horizontal springs m^2 determine the mass of the particle. The vertical
springs make up an harmonic oscillator at each point in space.
Canonical quantization is now done by treating these harmonic oscillators
as
quantum mechanical harmonic oscillators instead. The solutions
are the Gaussian Hermite functions which you can see here:
http://en.wikipedia.org/wiki/Quantum_harmonic_oscillator
The creation operator repeatedly applied to the ground state H0 gives
H1, H2, H3, ... Hn. The annihilation operator does the opposite and goes
the other way H3, H2, H1, H0. Operating on H0 gives 0. The number
operator gives back the value of n. The ground state H0 is denoted by |0>
The energy level of n particles is given by:
E_n \ =\ \left( n+\frac{1}{2} \right)\ \hbar \omega
Which quantizes the number of particles that can exist at a certain
frequency.
CANONICAL QUANTIZATION OF THE DIRAC FIELD
====================================
This is not that much different. Not in the last place because all the
individual spinor components obey the Klein Gordon equation.
CANONICAL QUANTIZATION OF THE EM FIELD
==================================
This is more tricker. Peshkin & Schroeder doesn't even discuss it. We
see the problem if we consider that the field is mass-less. The vertical
springs m^2 in our image above disappear and there is no more
harmonic oscillator. So, we need something else to take over this
function instead.
The EM field can be described, considering gauge invariance, with four
equations:\partial^2_t A^\nu\ =\ \partial_x^2 A^\nu +\partial_y^2 A^\nu +\partial_z^2 A^\nu \ +\ \partial^\nu \left( \partial_\mu A^\mu \right)
Where each value of \nu = 0,1,2,3 gives us one of the four equations.
It is clear that the last term should take over the role that the mass had
in the Klein Gordon equation in one way or another. However, the conserved
current rule for the EM field gives us:
\partial_\mu A^\mu \ =\ \partial_t V + \partial_x A_x + \partial_y A_y + \partial_z A_z \ =\ 0
Under this condition it is not possible to do a second quantization of the
EM field. Now, Gupta and Bleuler came up with a less restrictive rule:
\partial_\mu A^\mu \ \neq\ 0, \qquad \mbox{but} \quad \partial_\mu A^{(+)\mu} |\psi \rangle \ =\ 0
The latter means that if we consider only positive frequency parts then
these operating on a field should have a zero effect. This is what made
it possible to do a second quantization of the EM field.that's it.
Now personally I'm not fully satisfied with this solution, because the
source of the EM field, The charge/current density
is conserved.
That is:
\partial_\mu J^\mu \ =\ 0
And it is hard to see how this conserved current can give rise to a non-
conserved EM field, and worse: If the EM field is expressed as a plane
wave, going in the z-direction, for instance: (0,Ax,Ay,0), then all derivatives
in x and y are zero, and this also sets the last term to zero, the term we
need for second quantization, but OK. A good treatment of the EM field
can be found in:
Lewis H Ryder, Quantum Field Theory, chapter 4
Regards, Hans