tefavolc,
Maybe you should back up and tell us what you are trying to achieve. It is beginning to sound like you are attempting to build something like a Tesla coil or perhaps some type of high-voltage lighting ballast?
In any case, I now assume you have something like this in mind?
I further assume you are attempting to use "standard" 220V line transformers? This is going to prove problematic. You are using the "primary side" of the transformer as a secondary. Because the primary side was designed for a 220V line voltage with a very low impedance, the primary itself has a fairly high impedance, thus you cannot drive it properly with 12V.
In general transformers are rated by VA (Volt-Amps), with the rating reflecting the maximum power the transformer can transfer. In simplified terms, a 22VA transformer is designed for ~0.1A on the primary side. Assuming a 12V output, this would imply ~1.8A on the secondary side.
To drive this transformer in reverse, you would need to apply a 1.8A signal to the "secodary" (now technically the primary), and you should see ~220V on the "primary" (now technically the secondary) with a maximum current of ~0.1A.
But here comes the problem with connecting a second line transformer in series: You are now attempting to drive the low impedance side of a transformer from the high impedance side of another transformer. To simplify what is happening, let's consider this in terms of DC resistance:
220V = 0.1A * R => 2200ohms (DC approximation of Primary)
12V = 1.8A * R => 6.7ohms (DC approximation of Secondary)
When you connect the 6.7ohm secondary to the 2.2k primary, the resistance drops to: 1/((1/2200) + (1/6.7)) = 6.64 ohms ==> 6.64 ohms and the voltage drops to 6.64 ohms* 0.1A = 6.64V which, of course, means that the output of the second transformer will be less than the output of the first!
Obviously the actual AC case is more complicated than this simplified explanation, but this should demonstrate in simple terms what you are experiencing.
Fish