Construct a partition function for the system

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SUMMARY

The discussion focuses on constructing the partition function Q for a system comprising N noninteracting particles and a piston of mass M in a container. The Hamiltonian H(p,q) is defined as H(p,q) = ∑(p_i^2/2m) + mgy, leading to a 6N+1 dimensional phase space. The partition function Z is expressed as Z = (1/N!h^{3N}) ∫ e^{-\beta H(p,q)} d^3p d^3q dy. The user seeks clarification on the integration process to ensure the result aligns with the Gibbs potential for an ideal gas, A = -kT ln Z.

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Homework Statement



Consider a system of N noninteracting particles in a container of cross-sectional area A. Bottom of the container is rigid. The top consists of an airtight, frictionless piston of mass M. Neglect the potential energy of the molecules of gas.

Construct the partition function Q of the (N+1) particle system (N particles of mass m+ piston)

Calculate the fluctuations in the volume of the system?

Homework Equations


Z= \frac{1}{N!h^{3N}}\int e^{-\beta H(p,q)}d^3pd^3q

The Attempt at a Solution



System is in equilibrium for theory to be applicable, hence piston is at rest at some height y.

H(p,q) = \sum_i \frac{p_i^2}{2m} +mgy

6N+1 dimensional phase space

Z= \frac{1}{N!h^{3N}}\int e^{-\beta (\sum_i \frac{p_i^2}{2m} +mgy )}d^3pd^3q dy
 
Last edited:
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Addition: I did the integration for Z but the answer is not coming right. How do I know the answer? It SHOULD come out to be the same as the Gibb's potential for an ideal gas. ie A=-kTlnZ.
 

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