Chemistry Correct order of bond length in two organic molecules

AI Thread Summary
The discussion centers on determining the correct order of bond lengths in two organic molecules, with participants analyzing the stability and resonance effects on bond lengths. It is established that increased stability correlates with shorter bond lengths, and resonance can enhance stability. One participant concludes that molecule x participates in resonance, making it more stable than molecule y, leading to the assertion that x<y. However, there is a debate regarding the relationship between resonance and bond length, with conflicting views on whether more resonance leads to longer or shorter bonds. The conversation highlights the complexity of applying Hückel's rules in this context.
randomgamernerd
Messages
139
Reaction score
4

Homework Statement

: [/B]The correct relation is:
A. x=y
B. x>y
C. x<y
D. None.
Please refer to picture attached.

Homework Equations

: [/B]As stability increases, bond length decreases. When a Π bond is delocalised i.e it takes part in resonance, stability increases.

The Attempt at a Solution


I think x takes part in resonance.
Hence x is more stable than y.
Thus x<y i.e C is correct option.
 

Attachments

  • image.jpg
    image.jpg
    26.9 KB · Views: 548
Physics news on Phys.org
Do you know the Hückel rules?
 
DrDu said:
Do you know the Hückel rules?
yeah, I know..the 4n + 2 Π electron rule...right?
 
Yes, do you see how to apply it here?
 
DrDu said:
Yes, do you see how to apply it here?

no..
 
more resonance = longer bond
 
AMan24 said:
more resonance = longer bond

Compared to what?
 
Back
Top