Could a Titan probe detect life with polarized light?

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SUMMARY

The discussion centers on the viability of using polarized light to detect life in Titan's hydrocarbon seas. It posits that if life exists, it would produce polymers with a specific handedness, leading to an enantiomeric excess. The conversation references the work of Blackmond (2011) regarding the non-biological origins of such excesses. While the detection of chiral molecules would be significant, participants caution against interpreting positive results as definitive evidence of life.

PREREQUISITES
  • Understanding of polarized light and its applications in chemical analysis
  • Familiarity with polymer chemistry and enantiomeric excess
  • Knowledge of Titan's hydrocarbon lakes and their chemical properties
  • Awareness of the origin of life theories and relevant literature, such as Blackmond 2011
NEXT STEPS
  • Research the methods for detecting chiral molecules in extraterrestrial environments
  • Study the implications of enantiomeric excess in the context of abiogenesis
  • Explore the chemical properties of Titan's hydrocarbon lakes and their potential for supporting life
  • Investigate the autocatalytic processes that may lead to homochirality in biological systems
USEFUL FOR

Astronomers, astrobiologists, chemists, and researchers interested in the origins of life and extraterrestrial environments.

newjerseyrunner
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I had a thought and was wondering if it's viable to detecting whether or not life exists in Titan's hydrocarbon seas, whether we get direct evidence or not.

Titan lakes are hydrocarbons, which likes to create twisted polymer chains. Nature (lightning, cosmic rays...) should produce polymers that twist to the left and to the right in equal quantities. If we take a sample of a Titan lake could we shine polarized light through it to detect the concentration of twisted polymers in both the right and left directions?

If only natural processes exist on Titan, the concentrations should be more or less equal, however, if evolutionary processes exist, life-form will only produce the polymer in the same handedness as it's parent, ergo there should be a subset of polymers that exist in one direction in significantly higher quantities than the other.
 
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I'm not sure that optical activity would be a good indicator of the presence of life. Many in the origin of life field have hypothesized that an enantiomeric excess of certain sugars and amino acids preceded the life and lead to the homochirality of life, not the other way around. Although no one has found any definitive answers yet, a variety of mechanisms have been proposed for the non-biological origin of such an enantiomeric excess through purely chemical or physical means. For a review, see for example Blackmond 2011. Phil Trans R Soc B. 366:2878. doi:10.1098/rstb.2011.0130.
 
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Interesting, thanks.
 
Ygggdrasil said:
Many in the origin of life field have hypothesized that an enantiomeric excess of certain sugars and amino acids preceded the life and lead to the homochirality of life, not the other way around. Although no one has found any definitive answers yet, a variety of mechanisms have been proposed for the non-biological origin of such an enantiomeric excess through purely chemical or physical means.
Although that would still be quite an encouraging find. If not life, we'd still have found a/the positive feedback loop that is the precursor to life.
 
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DaveC426913 said:
Although that would still be quite an encouraging find. If not life, we'd still have found a/the positive feedback loop that is the precursor to life.
Absolutely. Discovering chiral molecules there and understanding how they got there would be a huge leap forward for the origin of life field. The experiment (if feasible) is certainly worth doing. I'd just argue against interpreting a positive result as definitive evidence for life on Titan.
 
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Oh, that's an interesting tangent i never thought of
 
I think that due to the "autocatalytic" nature of life any small excess of one form soon becomes a 100:0 ratio, so I think it is a good indicator. I think whenever possible extra planetary missions and observations will look for chiral molecules.
 
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