In conductors, excess positive charge does not exist as conductors remain overall charge-neutral. The movement of charge in conductors is primarily due to free electrons, not positive charge carriers. Positive charge distribution occurs on the surface of the conductor, but it is a result of the absence of electrons rather than an actual presence of positive charges. The concept of hole charges, which represent the absence of electrons, is also relevant in discussing charge distribution. Understanding these principles is essential for grasping electrical conduction in materials.