- 32,814
- 4,726
simon009988 said:I was thinking that If Electrons Don't move then how would you explain electricity? Would the whole wavefunction move?
You then have shifted gear. The ORIGINAL question was on electrons bound within an atom. Now, you're asking about the conduction electrons in metals which are now described NOT as electrons bound to an atom, but rather to the whole bulk crystal with Bloch functions. This is now governed by a different description. The Bloch wavefunction now describes such a process if you want to be accurate. However, in many instances, a "free electron gas" description is often good enough. Ohm's law, for example can be derived from such a scenerio.
Do not be confused between the use of QM description in some circumstances with the use of classical description with it is called for under other circumstances. Electrons in particle accelerators are very often described via classical description. However, such usage in the atomic scenario will lead to absurd and self-contradicting results.
Zz.