Do Photons Move Slower in a Solid Medium? - Comments

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Discussion Overview

The discussion revolves around the behavior of photons in solid media, particularly focusing on their speed and interaction with materials. Participants explore concepts related to light propagation, absorption, and the role of various excitations in solids, including phonons and electronic excitations.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants question how mirrors function and the nature of light absorption in translucent materials, considering whether it is probabilistic or related to particle interactions.
  • One participant argues that electronic excitations are more significant than phonons in explaining light dispersion in visible light, suggesting that the electric field of light can induce polarization in electron clouds, leading to a reduction in phase velocity.
  • Another participant challenges the dominance of the phonon polariton model at optical frequencies, asserting that dipole interactions with bound electrons are more relevant and noting a distinction between polaritons and excitons.
  • A later reply corrects a previous statement regarding the analogy between excitons and phonons, clarifying the terminology used in the context of polaritons.

Areas of Agreement / Disagreement

Participants express differing views on the significance of phonons versus electronic excitations in the context of light propagation in solids. The discussion includes contested interpretations of how photons interact with materials, indicating that multiple competing views remain.

Contextual Notes

Participants reference various models and interactions without resolving the complexities of these interactions or the conditions under which they apply. There is an acknowledgment of the need for further clarification on the roles of different excitations in light behavior.

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Do Photons Move Slower in a Solid Medium?

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Some questions come to my mind.
1. Can you try to explain how a mirror actually works?
2. Can you expand a bit on translucent materials? Why do some photons get absorbed and others don't? Is the absorption probabilistic, or can it be understood as a cloud of opaque particles in transparent media?
 
I don't think that phonons are that important to explain dispersion of light in the visible region as addressed in this article. Much more important are electronic excitations of the atoms and molecules making up the substance. If these excitations are coupled, one speaks of excitons in analogy to photons. In deed the electrons have a much larger oscillator strength as compared with the phonons.
Although in transparent media like glass, the eigenfrequencies -or rather broad absorption bands - of these modes lie in the ultraviolet region of the spectrum, they can influence the propagation of light in the visible region. The point is that, though nonresonant, the electric field of the light wave can drive forced polarization of the electron clouds. Now ,- well below the resonance frequency - while the phase of the polarisation will be in phase with the driving field, the electric field radiated by the polarisation will lag behind by 90 degrees. This increasing phase lag is nothing else but a reduction of phase velocity.
 
Correct me if I’m wrong but I think that the phonon polariton model described in this article is dominant only at very far infrared frequencies. I believe the dipole interaction with bound electrons becomes dominant at optical frequencies. (I thought a dressed photon state was called a polariton, not an exciton, by the way.)

It might be worth mentioning therefore that this article describes one example of the various ways photons interact with collective excitations?
 
Daz, you are obviously right, I wanted to say "in analogy to phonons" not photons. One can speak of exciton-polaritons and phonon-polaritons.
 

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