rede96 said:
Although I appreciate this line of discussion is probably just academic at best, where is the boundary between macro and micro systems? How small do I need to go before it can be said that all properties of a system can remain unchanged over time?
There's not a hard limit. It depends on how well you can isolate your system. Maybe a few atoms, or more if you can cool your system to nanokelvins.
rede96 said:
Even if I think of a Hydrogen atom, the electron and proton have properties like spin.
Let's start with the spin of a single electron in an external magnetic field, for simplicity. If the external magnetic field stays constant, then the spin of the electron will have two energy eigenstates. One is aligned with the magnetic field and one is in the opposite direction. If the spin is in one of these states, it will stay constant in time, provided you don't disturb it. The spin of the electron can also be not aligned with the magnetic field, but then it is not in an energy eigenstate, and it will change in time.
You can choose to measure the spin along any direction you want. If you measure it along the direction of the external magnetic field, then you will force the spin to change to one of the energy eigenvalues, pointed either parallel or antiparallel to the field, and it will stay fixed there until something happens.
Or you can measure it along some other direction, in which case it will be forced away from an energy eigenstate, and it will continually rotate in time until something happens.
An atom is somewhat more complicated because in an energy eigenstate, the spin of the electron is coupled with the orbit of the electron, so it does not have a fixed value.