Bob Enyart said:
The intro to Wikipedia's article on the one-way speed of light has a standalone sentence that states, "The 'speed of light' in this article refers to the speed of all electromagnetic radiation in vacuum."
Wikipedia's phrasing might be misleading you. There are two distinct concepts involved here:
(1) The invariant speed--the speed which is the same in all reference frames.
(2) The speed of electromagnetic radiation in vacuum.
It just so happens that #1 and #2 are the same in our universe. But they are still different conceptually. Einstein clock synchronization, conceptually, involves #1, not #2; we are simply fortunate that #2 happens to be the same as #1 in our universe, so we have an easy way of physically realizing #1, by using EM radiation in vacuum.
Bob Enyart said:
I'm wondering if that clarification is needed.
As the above should make clear, yes, it is. If you try to use EM radiation not in a vacuum to define your clock synchronization, the problem is not that the speed of the radiation is slower than its speed in a vacuum; the problem is that the speed of the radiation is no longer invariant--it's no longer the same as #1 above, so the logic that allows you to use #2 as a physical realization of #1 breaks down.
Bob Enyart said:
Would discussions of Einstein's Synchrony Convention be just as accurate if they dropped the "vacuum" context
It depends on what you mean by "just as accurate". As above, the point of the Einstein synchronization convention is that speed #1 above is invariant--it's the same in all reference frames--and speed #2, in our universe, is the same as speed #1, so we can use speed #2 as a physical realization of an invariant speed. But obviously you can only use EM radiation in a vacuum to do this, since, as above, the speed of EM radiation not in a vacuum is not the same as speed #2 above and is therefore not the same as speed #1 above.
However, if you have a set of clocks that have been synchronized using the Einstein convention correctly (i.e., using EM radiation in a vacuum to perform the synchronization), then you can use those clocks to measure the one-way speed of anything you like, including EM radiation not in a vacuum.
But in any case, as
@Ibix has pointed out, your measured one-way speed will still be dependent on the clock synchronization you used; if you synchronized your clocks using some different method than the Einstein convention, you might measure a different one-way speed even for EM radiation in a vacuum. So there is no way of avoiding the fact that any one-way speed measurement requires a clock synchronization convention.