Brewster's Law can apply to opaque materials, but caution is needed in defining the refractive index. The law is relevant when considering whether there is an angle where no p-polarized light is reflected or the angle of maximum polarization difference. The Fresnel equations are recommended for analyzing p-polarization in these cases. Opaque materials are often modeled with a complex index of refraction, which alters the results while keeping the formulas unchanged. Understanding these nuances is essential for accurate application of Brewster's Law to opaque materials.