The range equation indeed provides two solutions for complementary angles, except in the case of maximum range, which is uniquely 45°. When solving for an angle given a specific range, both θ and 90°-θ are valid solutions, unless dealing with an inclined plane. In scenarios involving elevation changes, the solutions adjust to account for the incline angle. While both solutions exist mathematically, practical considerations may favor one angle over the other due to factors like drag and ease of execution. Understanding these principles helps illustrate the real-world applications of physics concepts.