Drawing resonance structure for SO42

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SUMMARY

The sulfate ion (SO42-) has six resonance structures, which reflect the distribution of formal charges across the molecule. While a structure with single bonds is theoretically a possible resonance form, it is not favored due to significant charge separation, resulting in decreased stability. The primary resonance structures are those that minimize formal charges and maximize stability, contributing more significantly to the resonance hybrid.

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Sunwoo Bae
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Homework Statement
Draw the important resonance forms for SO42-
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I was told that there are six resonance structures for SO42-, as shown below.

1612005103934.png


I am wondering why this structure with single bonds is not one of the possible resonance.
I understand that it is unfavorable as the formal charges are spread out over all four atoms, but shouldn't is still be a part of the resonance, given that the total formal charge of the molecule adds up to 2- in total?

1612005230638.png


Thank you
 
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Theoretically that is a possible resonance structure, but that degree of charge separation makes it much less stable than the other structures, so it contributes very little to the resonance hybrid.
 

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