Well, the converse of the first one would be: if the eigenfunctions of an operator are complete then the operator is hermitian.
the second would be: if the eigenfunctions of a hermitian operator belong to distinct eigenvalues then the eigenfunctions are orthogonal.
and the third is: If the eigenvalues of an operator are real then the operator is hermitian
Actually I don't think 2 and 3 are correct so that leaves #1.
I've looked online but can't seem to find it
Hope that clarifies it
If the eigenvectors of an operator A form a complete orthonormal set {|i \rangle}, then you can write the operator A (in terms of its eigenvalues) as
A = \sum a_{i}|i \rangle \langle i |
Thus
\{A = A^{\dagger}\} \Leftrightarrow \{ a_{i} = a_{i}^{\ast}\}
So, your first statement is wrong while 2 and 3 are correct.
sam