Elements that react with crystalline

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The discussion centers on the factors that can cause crystalline structures to lose their organized patterns. Various reactions can lead to a loss of crystallinity, with oxidation and solvation by solvents like water being common examples. It is noted that solvation may not strictly qualify as a "reaction" in a chemical sense. The conversation also touches on liquid crystals, which are unique in that they can form a periodic array when subjected to an electric field, resembling a quasicrystal. Unlike traditional crystals, liquid crystals do not involve the formation or breaking of chemical bonds under an electric field, leading to induced crystallinity. The analogy to magnetic domains in ferromagnets is mentioned, highlighting the complexity of molecular interactions within liquid crystals, where some areas remain amorphous despite the presence of long-range order.
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What element will react with crystalline causing it to lose it's organized pattern.
 
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There are hundreds of reactions involving crystals that result in loss of crystallinity. A common example is oxidation.
 
Or if its a soluble crystal, a solvent like water.
 
Almost all chemical processes will, as long as the product itself is not crystalline.
 
3trQN said:
Or if its a soluble crystal, a solvent like water.
That was my first thought, but I wasn't sure how rigorous the OP was by the use of the term 'element'.
 
Gokul43201 said:
That was my first thought, but I wasn't sure how rigorous the OP was by the use of the term 'element'.

Yeah, i don't think it even classes as a "reaction", to a chemist. Solvation that is. Where reaction implies a chemical reaction.

I don't know much about liquid crystals, but they could also be an exception to that rule...intresting one too.
 
3trQN said:
I don't know much about liquid crystals, but they could also be an exception to that rule...intresting one too.
Liquid crystal is a long polar molecule (chiral too I think).
AFAIK it is not any sort of crystal in the chemical sense.
However, when in an electric field the heads and tails line up and form a periodic array. A sort of quasicrystal that polarizes light. Without the electric field they just asume a random orientation.
 
I see, by quasi-crystal do you mean that the liquid develops regions of crystaline structure and some where it is still amorphous? Or that its only an induced crystallinity and not a natural one?

These are similar to magnetic domains in ferromagnets no?
 
3trQN said:
I see, by quasi-crystal do you mean that the liquid develops regions of crystaline structure and some where it is still amorphous? Or that its only an induced crystallinity and not a natural one?
The nature of the beast is such that you will have molecules that don't cooperate. So you will have some residual amorphous areas.

Primarily I just mean that, with an electric field, the liquid crystal molecules form a periodic array. Much the same way that an ordinary crystal is a periodic array of molecules or atoms. Unlike the ordinary crystal there are no chemical bonds being formed or broken as the electric field is applied. Induced crystallinity.

3trQN said:
These are similar to magnetic domains in ferromagnets no?
I suppose there is some anology here.
I don't think I would go to far with it though.
 
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Right you are, thanks.
 
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NoTime said:
Liquid crystal is a long polar molecule (chiral too I think).
AFAIK it is not any sort of crystal in the chemical sense.
However, when in an electric field the heads and tails line up and form a periodic array. A sort of quasicrystal that polarizes light. Without the electric field they just asume a random orientation.
Not true.

In the complete absense of applied external fields, you can have both long-range anisotropy as well as long-range positional ordering. It only takes an electric field to make a macroscopic single-crystal.

This is loosely analogous to the magnetization of a ferromagnet.
 
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