Energies of interaction between molecules

AI Thread Summary
The discussion focuses on estimating the interaction energies between hydrogen and nitrogen molecules at 25 °C, separated by 0.3 nm, using the London dispersion force equation. Participants confirm the use of the equation V = -3/4 α²I/r⁶ for calculations. Concerns are raised about obtaining the polarizability values needed for the calculations, with a suggestion to refer to the textbook by Hirschfelder, Curtiss, and Bird for these values. The approach taken in the calculations is generally supported by other contributors. Accurate molecular properties are essential for determining the interaction energies effectively.
burns96
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Homework Statement


Estimate the energies of interaction at 25 °C between (i) two hydrogen molecules and (ii) two nitrogen molecules, if each pair is separated by 0.3 nm. Explain fully and clearly your reasoning and any assumptions you make in your answer. State the source of the values of any molecular properties you use in your calculation.

Homework Equations


Would I use the London dispersion force equation for this?
V = -3/4 α2I/r6

The Attempt at a Solution


so for hydrogen -3/4 x α2 x 1312 x 103/(3 x 10-10)6
Is this the right approach? Not sure where to get a value for polarisability from
 
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burns96 said:

Homework Statement


Estimate the energies of interaction at 25 °C between (i) two hydrogen molecules and (ii) two nitrogen molecules, if each pair is separated by 0.3 nm. Explain fully and clearly your reasoning and any assumptions you make in your answer. State the source of the values of any molecular properties you use in your calculation.

Homework Equations


Would I use the London dispersion force equation for this?
V = -3/4 α2I/r6

The Attempt at a Solution


so for hydrogen -3/4 x α2 x 1312 x 103/(3 x 10-10)6
Is this the right approach? Not sure where to get a value for polarisability from

This looks right to me.
Polarizabilities should be given in Hirschfelder, Curtiss, and Bird.
 
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