Energy bands in plastic materials

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Plastic materials exhibit large energy gaps between their valence and conduction bands, which influences their electrical properties. The valence band in plastics is characterized by a lack of free electrons, contributing to their insulating behavior. Plastics melt more easily than glass due to weaker intermolecular forces, rather than energy band structures. The melting process is primarily determined by these molecular attractions, not by the energy bands. For effective searches, terms like "energy bands in plastics" may yield limited results, as the focus should be on molecular interactions and properties.
Edward Wij
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Plastic materials are said to have large gaps between the valence band and the conduction band. But what is its valence band properties? Why do plastic melt easily compared to the glass? What is the relationship between energy bands and melting? And what are the right words in goggling this? "Energy bands in plastics" has zero hits.
 
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