Energy levels and hydrogen atom

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Discussion Overview

The discussion centers on the energy levels of a hydrogen atom and the nature of a solitary proton (H+). Participants explore whether a proton can be considered an atom and the conditions under which energy levels arise in the hydrogen atom system.

Discussion Character

  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants question whether a solitary proton has energy levels, suggesting that energy levels emerge only when the proton and electron interact.
  • One participant asserts that it is the proton-electron system that possesses discrete quantized bound states, not the solitary proton.
  • There is a discussion on whether a solitary proton can be regarded as an atom, with some arguing that from a physics perspective, it is likely not considered an atom, while others note that in chemistry, H+ behaves similarly to other singly-ionized atoms.
  • One participant proposes an analogy comparing the interaction of the electron and proton to the interaction of iron filings with a magnetic field, though they clarify that the phenomena are fundamentally different.
  • Another participant describes the energy levels of the hydrogen atom as resulting from the electrostatic interaction between the proton and electron, viewed through quantum mechanics and classical electromagnetism.

Areas of Agreement / Disagreement

Participants do not reach a consensus on whether a solitary proton can be considered an atom, and there are differing views on the nature of energy levels in relation to the proton-electron system.

Contextual Notes

Participants express uncertainty regarding the definitions of "atom" and the conditions under which energy levels are defined, highlighting the dependence on the context of physics versus chemistry.

brianhurren
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if you take a hydrogen atom and strip off the electron so that you are left with a proton. does the proton have energy levels around it? can a solitary proton still be regarded as an atom (H+)
 
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brianhurren said:
if you take a hydrogen atom and strip off the electron so that you are left with a proton. does the proton have energy levels around it?
No. It is the system proton+electron that posesses discrete quantized bound states.

brianhurren said:
can a solitary proton still be regarded as an atom (H+)
It depends in what regards. From the point of view of physics, the answer is most probably no. I don't think the people at CERN think they are colliding atoms when they are colliding protons. But for chemists, H+ has many of the same characteristics of other singly-ionized atoms, and is to be treated as a cation when considering chemical reaction.
 
so the energy levels emerge only when the electron and the proton interact. are the energy levels a result of the fact that the electron and proton charges are quantized?. Is that like when iron fillings and magnetic field interact and produce field lines?(analogy only, completely different phenomenon)
 
In the first approximation, the energy levels of the H-atom are due to the electrostatic interaction between a proton and an electron as electrically charged particles, with these 2 particles seen through the eyes of quantum mechanics, while the interaction between them is in terms of classical electromagnetism (electrostatics).
 

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