Enthalpy of System: Dissolving NaCl in Water

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The dissolution of NaCl in water is an endothermic process, with a change in enthalpy of approximately +4 kJ/mol, indicating that the system absorbs heat. For 0.1 mol of NaCl, this results in an enthalpy increase of about +0.4 kJ, contradicting the initial assumption that dissolution lowers the system's enthalpy. The heat absorbed by the system leads to a rise in temperature, suggesting that the enthalpy of the system increases rather than decreases. The stabilization of ions by water molecules also plays a significant role in this process, which complicates the analysis. Therefore, it is concluded that the dissolution of NaCl does not result in a lower enthalpy of the system.
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Homework Statement



Consider the dissolving of NaCl in water. Assume the system consists of 0.1 mol NaCl and 1 L of water. Considering that the NaCl readily dissolves in the water and that the ions are strongly stabilized by the water molecules, is it safe to conclude that the dissolution of NaCl in water results in a lower enthalpy of the system? Explain your response.

Homework Equations



E = q + w
H = q
possibly
Ek = 0.5mv^2
Epot = 8.99x10^9(Q1)(Q2)/d

The Attempt at a Solution



The change in enthalpy for the dissolution of NaCl is -0.2kJ per mole and for 0.1 mole NaCl is -0.02 kJ. This heat will be transferred to the H2O which is included in the system and so the heat of the system will rise. This conclusion ignores the stabilization effect of the water molecules (something not even covered in the book at this point). I would guess that the kinetic energy of the individual Na+ and Cl- ions requires work from the H2O molecules for stabilization and that the the two values would be equal and thus cancel. So:
E = q --- q = H and q is positive so the enthalpy of the system H = Hfinal - Hinitial, where Hfinal is larger than Hinitial due to the NaCl dissolution.

I really have no idea if what I just wrote makes any sense or not. Please help me.
 
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The dissolution of NaCl in water is an endothermic reaction: my data say +4 kJ/mol.
if the system is isolated, then T will drop. If we assume the system is isothermal, heat will enter the system (Q=0.4kJ), and the enthalpy will increase with this amount (dH=Q).
Hence the answer is NO.
 
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