Equilibrium Constant Keq: 2H2S(g) <-> H2(g) + S2(g) at 830°C

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The equilibrium constant (Keq) for the reaction 2H2S(g) <-> 2H2(g) + S2(g) at 830°C is 4.20x10^-6, indicating that reactants are favored over products. The discussion involves calculating the expected concentration of S2 at equilibrium after injecting 0.200 mol of H2S into a 1.00 L flask. Participants are attempting to solve for the variable x using an ICE table and the law of mass action, but some are struggling with the resulting cubic equation. Clarification is sought on the correct formulation of the equation, particularly regarding the presence of 4x^3. The conversation emphasizes the importance of understanding equilibrium principles to accurately determine the reaction's favorability.
Fusilli_Jerry89
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The value of Keq for the reaction: 2H2S(g) <-> 2H2(g) + S2(g) is 4.20x10^-6 at 830 degrees celsius.
a) What is favoured in this reaction, reactants or products?
b) What concentration of S2 can be expected at equilibrium after 0.200 mol of H2S is injected into an empty 1.00 L flask?
 
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a) Do you know how to write out Keq? (Hint: Use the law of mass action).
b) Make an ice box
2H2S(g) <--> 2H2(g) + S2 (g)
i .200 0 0
c -2x +2x +x
e .200 - 2x 2x x

Keq = [((2x)^2)(x)] / [(.200 - 2x)^2]
 
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i solved x to equal 1.431 but when u plug it back into the original question, H2S comes out to a negative number
 
oh nm i made a mistake
 
k got down to 4x^3-1.68x10^-5x2+3.36x10^-6-1.68x10^-7=0 now what
 
Fusilli_Jerry89 said:
k got down to 4x^3-1.68x10^-5x2+3.36x10^-6-1.68x10^-7=0 now what
What does that mean?

Look to your rules of equilibrium to determine which side of the reaction is favoured.

As for x, you can solve for it.
 
i put the products are favoured, but i do not know how to solve this equation because it has an 4^3 x^2 and an x
 
Fusilli_Jerry89 said:
i put the products are favoured, but i do not know how to solve this equation because it has an 4^3 x^2 and an x
Why do you have 4x^{3} in your equation? Solve for x.
 
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